Volume 43 Issue 10
Oct.  2015
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Article Navigation >  Journal of Fuel Chemistry and Technology  > 2015  >  43(10): 1202-1214
WANG Sen, CHEN Yan-yan, WEI Zhi-hong, QIN Zhang-feng, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Recent research progresses in the effect of framework structure and acidity of zeolites on their catalytic performance in methanol to olefins (MTO)[J]. Journal of Fuel Chemistry and Technology, 2015, 43(10): 1202-1214.
Citation: WANG Sen, CHEN Yan-yan, WEI Zhi-hong, QIN Zhang-feng, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Recent research progresses in the effect of framework structure and acidity of zeolites on their catalytic performance in methanol to olefins (MTO)[J]. Journal of Fuel Chemistry and Technology, 2015, 43(10): 1202-1214.
shu

Recent research progresses in the effect of framework structure and acidity of zeolites on their catalytic performance in methanol to olefins (MTO)

  • 1.

    State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

  • 2.

    University of Chinese Academy of Sciences, Beijing 100049, China

Funds:  The project was supported by the National Natural Science Foundation of China (21227002, 21573270, 21273264, 21273263), National Basic Research Program of China (Program 973, 2011CB201400) and Natural Science Foundation of Shanxi Province of China (2013021007-3, 2012011005-2).
  • Received Date: 2015-06-10
  • Rev Recd Date: 2015-09-04
  • Publish Date: 2015-10-31
    Abstract
  • The conversion of methanol to olefins (MTO), as a non-petroleum route to get valuable chemicals from multifarious carbon resources such as coal, natural gas and biomass, has attracted extensive attentions in recent years. The catalytic performance of acidic zeolites used in MTO is closely related to their framework structure and acidic properties; a clear understanding on this relation is of benefits to the development of better zeolite catalysts and improvement of current processes for MTO. Therefore, in this paper, we attempt to make a review on the recent research progresses in the effect of framework structure and acidity of zeolites on their catalytic performance in MTO. The review was focused on the difference of various zeolites in the hydrocarbon pool species, reaction pathway and catalytic kinetics; especially, the relation between the framework structure and acidic properties of zeolites and their catalytic performance in MTO was expatiated.
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