Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization

LIU Han-lin; LI Xiu-ping; ZHAO Rong-xiang

Volume 48 Issue 3

Mar. 2020

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LIU Han-lin, LI Xiu-ping, ZHAO Rong-xiang. Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 369-377.

Citation:

LIU Han-lin, LI Xiu-ping, ZHAO Rong-xiang. Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 369-377.

LIU Han-lin, LI Xiu-ping, ZHAO Rong-xiang. Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 369-377.

Citation:

LIU Han-lin, LI Xiu-ping, ZHAO Rong-xiang. Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 369-377.

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Preparation of DESs/SG catalyst and its performance in the oxidative desulfurization

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
College of Chemistry & Material Science Engineering, Liaoning Shihua University, Fushun 113001, China

Funds:

The project was supported by the Mentoring Program Projects from Liaoning Natural Science Foundation 2019-ZD-0064

Received Date: 2019-10-21
Rev Recd Date: 2020-01-21

Available Online: 2021-01-23

Publish Date: 2020-03-10

Abstract

Abstract

DESs/SG catalyst was prepared by supporting the proline-based deep eutectic solvent (DES) on the silica-gel (SG) matrix using a sol-gel method; the catalyst structure was characterized by FT-IR, XRD, SEM/EDS and N₂ adsorption-desorption. The results showed that the DESs were successfully incorporated into the silica-gel matrix, leading to a decrease in the surface area and pore volume, but an increase in the pore diameter. With hydrogen peroxide as oxidant, the catalytic performance of DESs/SG in the oxidative desulfurization of a model oil containing dibenzothiophene (DBT) was investigated; the effects of deep eutectic solvent loading, reaction temperature, n(H₂O₂)/n(S) ratio, catalyst amount, sulfur compound type and catalyst recycle times on the desulfurization efficiency were considered. The results indicated that under optimum desulfurization conditions, the desulfurization degrees for DBT, 4, 6-dimethyl-dibenzothiophene (4, 6-DMDBT) and benzothiophene (BT) over the DESs/SG catalyst were 97%, 96.5% and 46.4%, respectively; after recycling for 9 times, the DESs/SG catalyst still displayed a desulfurization degree of above 89.4%.
- silica gel,
- oxidation desulfurization,
- deep eutectic solvents,
- sol-gel,
- dibenzothiophene

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References(42)

References

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