Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming

Agüero Fabiola Nerina; Alonso Jose Antonio; Fernández-Díaz Maria Teresa; Cadus Luis Eduardo

Volume 46 Issue 11

Nov. 2018

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Agüero Fabiola Nerina, Alonso Jose Antonio, Fernández-Díaz Maria Teresa, Cadus Luis Eduardo. Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1332-1341.

Citation:

Agüero Fabiola Nerina, Alonso Jose Antonio, Fernández-Díaz Maria Teresa, Cadus Luis Eduardo. Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1332-1341.

Citation:

Agüero Fabiola Nerina, Alonso Jose Antonio, Fernández-Díaz Maria Teresa, Cadus Luis Eduardo. Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1332-1341.

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Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming

1.
Instituto de Investigaciones en Tecnología Química(INTEQUI), UNSL-CONICET, Almirante Brown 1455, 5700 San Luis, Argentina
2.
Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Cantoblanco, 28049 Madrid, Spain
3.
Institut Laue-Langevin, B. P. 156, F-38042 Grenoble Cedex 9, France

More Information

Corresponding author: Luis Eduardo Cadus, E-mail:lcadus@unsl.edu.ar
Received Date: 2018-06-29
Rev Recd Date: 2018-09-19

Available Online: 2021-01-23

Publish Date: 2018-11-10

Abstract

Abstract

Perovskites as host structures of cations were used in order to generate in situ active and stable catalysts for ethanol steam reforming. For this purpose, La_1-xMg_xAl_1-yNi_yO₃ (x=0.1; y=0, 0.1, 0.2, 0.3) perovskites were synthetized by the citrate method. Ni segregation is evident for a substitution level higher than 0.2. The segregation of Ni as NiO generated species interacts with different metal-support after the reduction step. The y=0.1 catalyst presents the highest H₂ yield value about 85% during reaction time, with low mean values of CH₄ and CO selectivities of 3.4% and 11%, respectively and a low carbon formation. The better performance of y=0.1 catalyst could be attributed to the minor proportion of segregated phases, thus a controlled expulsion of Ni is successfully reached.
- perovskites,
- catalyst design,
- ethanol,
- steam reforming

本文的英文电子版由Elsevier出版社在ScienceDirect上出版(http://www.sciencedirect.com/science/journal/18725813).

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References(29)

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