Preparation of Ru/Co-Al-O supported catalysts and its hydrodeoxygenation properties

TAN Liang; MIAO Lei; WU Kui; WANG Wei-yan; YANG Yun-quan

Volume 46 Issue 2

Feb. 2018

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Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(2): 219-224

TAN Liang, MIAO Lei, WU Kui, WANG Wei-yan, YANG Yun-quan. Preparation of Ru/Co-Al-O supported catalysts and its hydrodeoxygenation properties[J]. Journal of Fuel Chemistry and Technology, 2018, 46(2): 219-224.

Citation:

TAN Liang, MIAO Lei, WU Kui, WANG Wei-yan, YANG Yun-quan. Preparation of Ru/Co-Al-O supported catalysts and its hydrodeoxygenation properties[J]. Journal of Fuel Chemistry and Technology, 2018, 46(2): 219-224.

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Preparation of Ru/Co-Al-O supported catalysts and its hydrodeoxygenation properties

School of Chemical Engineering, Xiangtan University, Xiangtan 411105, China

Funds:

the National Natural Science Foundation of China 21776236

the National Natural Science Foundation of China 21676225

Hunan Province Graduate Research and Innovation Funded Projects CX2017B334

More Information

Corresponding author: WANG Wei-yan, Tel:15973202675, E-mail:wangweiyan@xtu.edu.cn.
Received Date: 2017-08-30
Rev Recd Date: 2018-01-04

Available Online: 2021-01-23

Publish Date: 2018-02-10

Abstract

Abstract

Co-Al layered double hydroxides were prepared by co-precipitation method and converted into composite oxides via calcination.The composite oxide were then used to prepare a series of Ru/Co-Al-O supported catalysts.The structures and properties of the catalysts were characterized by XRD, BET and FT-IR.The hydrodeoxygenation (HDO) properties of these catalysts were tested by using 4-methylphenol as a typical oxygen-containing model compound of lignin biomass oil.This study concentrated on the effects of Co/Al molar ratio and the reduction temperature of the catalyst on the hydrodeoxygenation activity of Ru/Co-Al-O and the optimization of HDO temperature.The results showed that when the molar ratio of Co/Al was 3:1, the catalyst reduction temperature was 350℃ and the reaction temperature was 275℃, the HDO activity was the highest:both the conversion and deoxygenation degree in the HDO of p-methyl phenol reached up to 100%.
- hydrodeoxygenation,
- Co-Al layered double hydroxides,
- Ru,
- 4-methylphenol,
- composite oxides

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References(25)

References

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