Promoting effect of oxidation reaction on steam gasification reaction in Shengli lignite gasification processⅡ.Mechanism study

CHENG Xiang-long; WANG Yong-gang; SUN Jia-liang; SHEN Tian; ZHANG Hai-yong; XU De-ping

Volume 45 Issue 2

Feb. 2017

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Article Navigation > Journal of Fuel Chemistry and Technology > 2017 > 45(2): 138-146

CHENG Xiang-long, WANG Yong-gang, SUN Jia-liang, SHEN Tian, ZHANG Hai-yong, XU De-ping. Promoting effect of oxidation reaction on steam gasification reaction in Shengli lignite gasification processⅡ.Mechanism study[J]. Journal of Fuel Chemistry and Technology, 2017, 45(2): 138-146.

Citation:

CHENG Xiang-long, WANG Yong-gang, SUN Jia-liang, SHEN Tian, ZHANG Hai-yong, XU De-ping. Promoting effect of oxidation reaction on steam gasification reaction in Shengli lignite gasification processⅡ.Mechanism study[J]. Journal of Fuel Chemistry and Technology, 2017, 45(2): 138-146.

Citation:

CHENG Xiang-long, WANG Yong-gang, SUN Jia-liang, SHEN Tian, ZHANG Hai-yong, XU De-ping. Promoting effect of oxidation reaction on steam gasification reaction in Shengli lignite gasification processⅡ.Mechanism study[J]. Journal of Fuel Chemistry and Technology, 2017, 45(2): 138-146.

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Promoting effect of oxidation reaction on steam gasification reaction in Shengli lignite gasification processⅡ.Mechanism study

School of Chemical and Environmental Engineering, China University of Mining and Technology(Beijing), Beijing 100083, China

Funds:

12th Five-Year Plan of National Science and Technology Support 2012BAA04B02

More Information

Corresponding author: Te1:010-62339882,E-mail:wyg1960@126.com
Received Date: 2016-09-23
Rev Recd Date: 2016-11-29

Available Online: 2021-01-23

Publish Date: 2017-02-10

Abstract

Abstract

Shengli brown coal was gasified at 800-900℃ in a simulated entrained-flow reactor, φ 80×3 000 mm.The physical structure and functional groups of char were tested by infrared spectroscopy, X-ray photoelectron spectroscopy and Raman spectroscopy while coal gas was tested by gas on-line analysis instrument in order to explore the mechanism of promoting effect of oxidation reaction on steam gasification reaction.The results show that the synergy effects can be explained by dissociated adsorption reaction mechanisms of steam gasification reaction and semi-coke pore structure features under different atmospheres.The oxidation reaction can make microspores number, specific surface area, pore volume and adsorption capacity of the char particles greatly increase and more carbon active sites expose by producing microspores, developing mesopores;it also prompts small groups as-CH₃, -CH₂-, ＞ C=O & ＞ C-O-fractured and generation of hydrogen free-radical and carboxyl.All these promote steam gasification reaction rate, especially at a higher water vapor content or temperature.Meanwhile, the oxidation reaction can change the relative content of CO₂, CO, H₂ and internal energy of steam molecules and activated carbon atoms, in favor of steam gasification reaction.
- mild gasification,
- synergistic effect,
- steam gasification,
- pore structure,
- dissociated adsorption

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References(34)

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