Shengli lignite liquefaction under syngas and complex solvent

LI Qiang-lin; CHEN Zhuo; ZHOU Qun; DAI Li; LI Liang; WU Shi-yong

Volume 44 Issue 3

Mar. 2016

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Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(3): 257-262

LI Qiang-lin, CHEN Zhuo, ZHOU Qun, DAI Li, LI Liang, WU Shi-yong. Shengli lignite liquefaction under syngas and complex solvent[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 257-262.

Citation:

LI Qiang-lin, CHEN Zhuo, ZHOU Qun, DAI Li, LI Liang, WU Shi-yong. Shengli lignite liquefaction under syngas and complex solvent[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 257-262.

LI Qiang-lin, CHEN Zhuo, ZHOU Qun, DAI Li, LI Liang, WU Shi-yong. Shengli lignite liquefaction under syngas and complex solvent[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 257-262.

Citation:

LI Qiang-lin, CHEN Zhuo, ZHOU Qun, DAI Li, LI Liang, WU Shi-yong. Shengli lignite liquefaction under syngas and complex solvent[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 257-262.

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Shengli lignite liquefaction under syngas and complex solvent

LI Qiang-lin¹,
CHEN Zhuo¹,
ZHOU Qun¹,
DAI Li¹,
LI Liang¹,
WU Shi-yong^{1, 2
,
,}

1.
College of Resource & Environmental Engineering, Shanghai 200237, China
2.
Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China

Funds:

National Natural Science Foundation of China 21476079

National Natural Science Foundation of China 21476080

and the Fundamental Research Funds for the Central Universities WB1414014

Received Date: 2015-07-08
Rev Recd Date: 2015-12-21

Available Online: 2021-01-23

Publish Date: 2016-03-30

Abstract

Abstract

The liquefaction of Shengli lignite (SL) were studied in the system of syngas (H₂+CO) and complex solvent (H₂O+THN) and the system of hydrogen (H₂) and tetralin (THN). Asphaltene (AS) and preasphaltene (PA) from the two systems were characterized by FT-IR. The results show that both conversion and oil yield of Shengli lignite liquefaction in the (H₂+CO)/(H₂O+THN) system are significantly higher than those in the H₂/THN system. The conversion and oil yield under syngas (H₂:CO=1:1) and complex solvent (THN:H₂O=1:1) reach respectively 88.79% and 55.47% at 400℃, 4MPa and 30min. The differences in the conversion and oil yield between the (H₂+CO)/(H₂O+THN) and H₂/THN systems are 8.00% and 7.54%, respectively. This suggests that the water-gas shift reaction can produce active hydrogen in the (H₂+CO)/(H₂O+THN) system, which benefits the hydrogenation of SL and PA. Meanwhile, THN can stabilize the free radicals from SL pyrolysis and dissolve the products (AS and PA) from SL liquefaction. The synergistic effect of two factors results in the improvement of conversion and oil yield. This study shows that it is a new lignite liquefaction technology using the (H₂+CO)/(H₂O+THN) system.
- syngas,
- complex solvent,
- Shengli lignite,
- direct liquefaction

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References(16)

References

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