Catalytic conversion of sweet sorghum stalk juice to furan compounds over H<i>β</i> zeolite

ZHENG Hong-yan; WANG Yue-qing; CHANG Xi-liang; NIU Yu-lan; YANG Hong; SONG Yong-bo; YAO Ying; DING Guo-qiang; ZHU Yu-lei

Volume 47 Issue 5

May 2019

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Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(5): 605-610

ZHENG Hong-yan, WANG Yue-qing, CHANG Xi-liang, NIU Yu-lan, YANG Hong, SONG Yong-bo, YAO Ying, DING Guo-qiang, ZHU Yu-lei. Catalytic conversion of sweet sorghum stalk juice to furan compounds over Hβ zeolite[J]. Journal of Fuel Chemistry and Technology, 2019, 47(5): 605-610.

Citation:

ZHENG Hong-yan, WANG Yue-qing, CHANG Xi-liang, NIU Yu-lan, YANG Hong, SONG Yong-bo, YAO Ying, DING Guo-qiang, ZHU Yu-lei. Catalytic conversion of sweet sorghum stalk juice to furan compounds over Hβ zeolite[J]. Journal of Fuel Chemistry and Technology, 2019, 47(5): 605-610.

Citation:

ZHENG Hong-yan, WANG Yue-qing, CHANG Xi-liang, NIU Yu-lan, YANG Hong, SONG Yong-bo, YAO Ying, DING Guo-qiang, ZHU Yu-lei. Catalytic conversion of sweet sorghum stalk juice to furan compounds over Hβ zeolite[J]. Journal of Fuel Chemistry and Technology, 2019, 47(5): 605-610.

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Catalytic conversion of sweet sorghum stalk juice to furan compounds over Hβ zeolite

1.
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China
2.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
Synfuels China Co. Ltd., Beijing 101407, China

Funds:

The project was supported by the National Science Foundation of China 21875276

Received Date: 2019-01-17
Rev Recd Date: 2019-02-20

Available Online: 2021-01-23

Publish Date: 2019-05-10

Abstract

Abstract

The conversion of sweet sorghum stalk juice rich in sucrose, glucose and fructose to furan compounds (5-hydroxymethylfurfural or furfural) was investigated over Hβ zeolite in γ-butyrolactone solvent. The results indicated that the main product for the conversion of sweet sorghum stalk juice (SSSJ) was 5-hydroxymethylfurfural; however, high yield of furfural was obtained in the conversion of model sweet sorghum stalk juice (MSSSJ) containing the same amount of hexose under the same conditions. The ²⁷Al MAS NMR results showed that ion-exchange took place between the Hβ zeolite and alkaline ions (mainly potassium) in the sweet sorghum stalk juice, resulting in the transformation of octahedrally coordinated aluminum into tetrahedrally coordinated framework aluminum. As an appropriate configuration environment of aluminum for Hβ was necessary for the formation of furfural from hexose, high yield of 5-hydroxymethylfurfural was achieved for the conversion of sweet sorghum stalk juice (SSSJ) due to the ion-exchange of Hβ with alkaline ions.
- sweet sorghum stalk juice,
- Hβ,
- furan compounds,
- furfural,
- 5-hydroxymethylfurfural

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References(19)

References

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