Catalytic performance of MnOx/TiO2 prepared with different precursors in the oxidation of NO with O3

LIU Li-jun; SHEN Bo-xiong; SI Meng; ZHANG Hao-hao; YUAN Peng

Volume 45 Issue 5

May 2017

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LIU Li-jun, SHEN Bo-xiong, SI Meng, ZHANG Hao-hao, YUAN Peng. Catalytic performance of MnOx/TiO2 prepared with different precursors in the oxidation of NO with O3[J]. Journal of Fuel Chemistry and Technology, 2017, 45(5): 624-632.

Citation:

LIU Li-jun, SHEN Bo-xiong, SI Meng, ZHANG Hao-hao, YUAN Peng. Catalytic performance of MnO_x/TiO₂ prepared with different precursors in the oxidation of NO with O₃[J]. Journal of Fuel Chemistry and Technology, 2017, 45(5): 624-632.

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Catalytic performance of MnO_x/TiO₂ prepared with different precursors in the oxidation of NO with O₃

School of Energy & Environment, Hebei University of Technology, Tianjin 300401, China

Funds:

the National Research Program of China 2016YFC0209202

National Natural Science Foundation of Hebei Province E2016202361

Received Date: 2017-01-06
Rev Recd Date: 2017-03-09

Available Online: 2021-01-23

Publish Date: 2017-05-10

Abstract

Abstract

MnAc/TiO₂, MnCl/TiO₂ and MnN/TiO₂ were prepared by impregnation method using manganese acetate (MnAc), manganese chloride (MnCl₂) and manganese nitrate (Mn (NO₃)₂) as precursors, respectively. These catalysts were characterized by SEM, N₂ physisorption, H₂-TPR, O₂-TPD, XRD and XPS; their catalytic performance in the oxidation of NO with ozone (O₃) was investigated in a fixed bed reactor. The results illustrate that the MnAc/TiO₂ catalyst with manganese acetate as the precursor exhibits the highest activity among three catalysts, which is ascribed to its highly dispersible particles, large surface area and high content of surface Mn³⁺.
- ozone,
- manganese precursor,
- NO,
- catalytic oxidation

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References(40)

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