Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis

CHENG Chun-yuan; LIU Su-yao; WU Bao-shan

Volume 45 Issue 5

May 2017

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Article Navigation > Journal of Fuel Chemistry and Technology > 2017 > 45(5): 556-563

CHENG Chun-yuan, LIU Su-yao, WU Bao-shan. Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2017, 45(5): 556-563.

Citation:

CHENG Chun-yuan, LIU Su-yao, WU Bao-shan. Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2017, 45(5): 556-563.

CHENG Chun-yuan, LIU Su-yao, WU Bao-shan. Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2017, 45(5): 556-563.

Citation:

CHENG Chun-yuan, LIU Su-yao, WU Bao-shan. Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2017, 45(5): 556-563.

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Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis

CHENG Chun-yuan^{1, 2},
LIU Su-yao^{3, 4},
WU Bao-shan^{1, 3, 4
,
,}

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
National Engineering Laboratory for Indirect Coal Liquefaction, Beijing 101407, China
4.
Synfuels China Technology CO. LTD., Beijing 101407, China

Funds:

National Natural Science Foundation of China 21473229

Received Date: 2017-01-16
Rev Recd Date: 2017-03-14

Available Online: 2021-01-23

Publish Date: 2017-05-10

Abstract

Abstract

Series of Ru-based F-T synthesis catalysts, respectively with different supports of SiO₂, Al₂O₃ and Beta zeolite, were prepared by impregnation method. Characterization techniques such as N₂-adsorption, XRD, NH₃-TPD, H₂-TPR, H₂-TPD, XPS and CO-DRIFTS were used to study the textural structure, phase, acidity, reduction behavior, chemical adsorption and electron properties of the catalysts. F-T synthesis performances of the catalysts were investigated as well. The results indicated that the supports imposed obvious effects on the reduction and dispersion of Ru, therefore led to the differences in acidity and surface properties of the catalysts. F-T reaction performance showed that the relatively stable Ru/SiO₂ catalyst exhibited high selectivity to heavy hydrocarbons, ascribing to its less acidity, weaker metal-support interaction, and better Ru particle dispersion.
- metal-support interaction,
- ruthenium catalyst,
- F-T synthesis

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References(32)

References

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