Preparation and characterization of Mo<sub>2</sub>N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil

TAN Qi-hang; CAO Yang; LI Jin

Volume 46 Issue 11

Nov. 2018

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Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(11): 1323-1331

TAN Qi-hang, CAO Yang, LI Jin. Preparation and characterization of Mo2N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1323-1331.

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TAN Qi-hang, CAO Yang, LI Jin. Preparation and characterization of Mo₂N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil[J]. Journal of Fuel Chemistry and Technology, 2018, 46(11): 1323-1331.

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Preparation and characterization of Mo₂N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil

TAN Qi-hang¹,
CAO Yang^{1, 2},
LI Jin^{1
,
,}

1.
State Key Laboratory of Marine Resource Utilization in South China Sea, College of Materials and Chemical Engineering, Hainan University, Haikou 570228, China
2.
Qiongtai Normal University, Haikou 571127, China

Funds:

the Hainan Provincial Key Projects ZDYF2018134

More Information

Corresponding author: LI Jin, Tel:15607608499, E-mail:316800681@qq.com
Received Date: 2018-07-17
Rev Recd Date: 2018-09-15

Available Online: 2021-01-23

Publish Date: 2018-11-10

Abstract

Abstract

MCM-41 and Zr-MCM-41 with different initial n(Si)/n(Zr) ratios were synthesized by hydrothermal method. Mo₂N/Zr-MCM-41 hydrodeoxygenation catalysts were prepared by (NH₄)₆Mo₇O₂₄ carrier co-impregnation, calaination, temperature programing and nitridation, and characterized by XRD, XPS, TEM and Py-FTIR methods. The catalytic performance of Mo₂N/Zr-MCM-41 in hydrodeoxygenation of Jatropha curcas oil was evaluated in a high pressure reactor. The results indicate that Zr modified carrier has the same pore structure as pure silicon MCM-41, and the value of L acid and B acid increases. As the active component, the Mo₂N has an excellent HDO performance. Under the reaction temperature of 350℃ and the hydrogen pressure of 3.0 MPa, the catalyzed product oil is mainly composed of straight chain alkanes and aromatic compounds, accounting for more than 90% of the product components. The deoxygenation rates of the new catalysts with different n(Si)/n(Zr) ratios are all above 98%, and the content of aromatic compounds is higher than that of straight chain alkanes, which accounts for 72.09% of the total composition. The aromatic compounds are mainly single ring and bicyclic aromatic hydrocarbons with the length of carbon chain of C_8-16. After the leprosy oils catalyzed by Mo₂N/Zr-MCM-41 are fractionated, it can be prepared to be biofuels.
- Mo₂N/Zr-MCM-41,
- hydrodeoxygenation,
- Jatropha oil,
- isomerization

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References(35)

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