Ag(Ⅰ)/(nC7H15)4NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO2 into β-oxopropylcarbamates

ZHAO Qing-ning; SONG Qing-wen; LIU Ping; ZHANG Kan; HAO Jian

Volume 46 Issue 8

Aug. 2018

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Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(8): 1009-1017

ZHAO Qing-ning, SONG Qing-wen, LIU Ping, ZHANG Kan, HAO Jian. Ag(Ⅰ)/(nC7H15)4NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO2 into β-oxopropylcarbamates[J]. Journal of Fuel Chemistry and Technology, 2018, 46(8): 1009-1017.

Citation:

ZHAO Qing-ning, SONG Qing-wen, LIU Ping, ZHANG Kan, HAO Jian. Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO₂ into β-oxopropylcarbamates[J]. Journal of Fuel Chemistry and Technology, 2018, 46(8): 1009-1017.

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Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO₂ into β-oxopropylcarbamates

ZHAO Qing-ning¹,
SONG Qing-wen^{2
,
,},
LIU Ping²,
ZHANG Kan^{2
,
,},
HAO Jian^{1, 3
,
,}

1.
Department of Chemistry, Shanghai University, Shanghai 200444, China
2.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
Basic Research Institute of Cultural Heritage Protection, Shanghai University, Shanghai 200444, China

Funds:

the National Natural Science Foundation of China 21602232

the National Natural Science Foundation of China 21672139

the Natural Science Foundation of Shanxi Province 201701D221057

More Information

Corresponding author: SONG Qing-wen, Tel:0351-4040012, E-mail:songqingwen@sxicc.ac.cn; ZHANG Kan, E-mail:zhangkan@sxicc.ac.cn; HAO Jian, E-mail:jhao@shu.edu.cn
Received Date: 2018-04-25
Rev Recd Date: 2018-06-20

Available Online: 2021-01-23

Publish Date: 2018-08-10

Abstract

Abstract

A simple dual-component catalytic system, i.e., Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr was applied for the synthesis of various β-oxopropylcarbamates via dual-component coupling of ammonium carbamates and propargylic alcohols under atmospheric pressure.This simple method was proved to be a highly efficient system without the use of ligand, and capable of converting various propargylic alcohols and secondary amines into corresponding organic carbamates.Notably, quantitative conversion of CO₂ was achieved, thus improved the efficiency of CO₂ utilization.
- CO₂ conversion,
- ammonium carbamates,
- silver catalysis,
- β-oxopropylcarbamates,
- synthetic method

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References(38)

References

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