Research on butene oligomerization reaction over the hemicellulose modified HZSM-5

LI Chao; WANG Hui; ZHU Shan-shan; LIU Guang-bo; WU Jin-hu

Volume 45 Issue 9

Sep. 2017

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Article Navigation > Journal of Fuel Chemistry and Technology > 2017 > 45(9): 1088-1094

LI Chao, WANG Hui, ZHU Shan-shan, LIU Guang-bo, WU Jin-hu. Research on butene oligomerization reaction over the hemicellulose modified HZSM-5[J]. Journal of Fuel Chemistry and Technology, 2017, 45(9): 1088-1094.

Citation:

LI Chao, WANG Hui, ZHU Shan-shan, LIU Guang-bo, WU Jin-hu. Research on butene oligomerization reaction over the hemicellulose modified HZSM-5[J]. Journal of Fuel Chemistry and Technology, 2017, 45(9): 1088-1094.

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Research on butene oligomerization reaction over the hemicellulose modified HZSM-5

LI Chao^{1, 2},
WANG Hui^{1
,
,},
ZHU Shan-shan^{1, 2},
LIU Guang-bo¹,
WU Jin-hu¹

1.
Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds:

the Chinese Academy of Sciences Research Program XDA07070302

the Applied Basic Research Programs of Qingdao 15-9-1-72-jch

the Foundation of state Key Laboratory of high-efficiency Utilization of Coal and Green Chemical Engineering 2016-11

More Information

Corresponding author: WANG Hui, Tel:0532-80662764, E-mail:huiwangsun@gmail.com
Received Date: 2017-03-28
Rev Recd Date: 2017-06-05

Available Online: 2021-01-23

Publish Date: 2017-09-10

Abstract

Abstract

The HZSM-5 synthesized with modifying by different contents of hemicellulose.The morphology, texture and acidity were characterized with XRD, SEM, N₂ adsorption-desorption, NH₃-TPD and Py-FTIR. Butene oligomerization over the modified HZSM-5 was tested. The results indicate that the HZSM-5 with the 1.6% hemicellulose exhibits the best activity and stability on the butene oligomerization reaction, the conversion can maintain about 80% after 140 h on stream, with the highest selectivities of the trimer, tetramer and diesel component in the products. These may be related with its high BET surface and mesoporous volume, and the strongest acidity.
- hemicellulose,
- modified,
- HZSM-5,
- butene oligomerization

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References(27)

References

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