Preparation of C9H10O2-0.5ZnCl2/Al2O3 and its oxidative desulfurization performance

LI Xiu-ping; ZHAO Rong-xiang; GONG Xiao-jie; LI Ping

Volume 47 Issue 10

Oct. 2019

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LI Xiu-ping, ZHAO Rong-xiang, GONG Xiao-jie, LI Ping. Preparation of C9H10O2-0.5ZnCl2/Al2O3 and its oxidative desulfurization performance[J]. Journal of Fuel Chemistry and Technology, 2019, 47(10): 1187-1194.

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LI Xiu-ping, ZHAO Rong-xiang, GONG Xiao-jie, LI Ping. Preparation of C₉H₁₀O₂-0.5ZnCl₂/Al₂O₃ and its oxidative desulfurization performance[J]. Journal of Fuel Chemistry and Technology, 2019, 47(10): 1187-1194.

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Preparation of C₉H₁₀O₂-0.5ZnCl₂/Al₂O₃ and its oxidative desulfurization performance

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China

Funds:

the Local Service Projects from Liaoning Education Department L2017LFW004

Received Date: 2019-05-23
Rev Recd Date: 2019-08-17

Available Online: 2021-01-23

Publish Date: 2019-10-10

Abstract

Abstract

A C₉H₁₀O₂-0.5ZnCl₂/Al₂O₃ catalyst was successfully prepared by immobilizing phenylpropionic acid-zinc chloride(C₉H₁₀O₂-0.5ZnCl₂) double acid deep eutectic solvent on Al₂O₃, and analyzed by XRD, FT-IR, SEM, EDS and N₂ adsorption-desorption. The removal activity for aromatic sulfides in model oil using C₉H₁₀O₂-0.5ZnCl₂/Al₂O₃ as catalysis and H₂O₂ as oxidant and the effect of some reaction parameters such as temperature, catalyst dosage, O/S molar ratio and different sulfide types on the desulfurization activity of catalyst were investigated. The experimental results show that with the model oil of 5 mL, the catalyst dosage of 0.2 g and the O/S molar ratio of 8, at temperature of 60℃and reaction time of 180 min, the removal rate of DBT can reach to 99.2%. In addition, the catalyst can be recycled up to 6 times with a little decrease in catalytic activity for the ODS process. The catalysis-oxidation desulfurization mechanism of C₉H₁₀O₂-0.5ZnCl₂/Al₂O₃ was also explored.
- zinc chloride,
- alumina,
- oxidation desulfurization,
- deep eutectic solvents

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References

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