Volume 44 Issue 3
Mar.  2016
Turn off MathJax
Article Contents
ZHANG Yu-kui, ZHANG Hai-xia, ZHU Zhi-ping. Physical and chemical properties of fly ash from fluidized bed gasification of Zhundong coal[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 305-313.
Citation: ZHANG Yu-kui, ZHANG Hai-xia, ZHU Zhi-ping. Physical and chemical properties of fly ash from fluidized bed gasification of Zhundong coal[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 305-313.

Physical and chemical properties of fly ash from fluidized bed gasification of Zhundong coal

Funds:

The project was supported by the National Natural Science Foundation of China 21306193

  • Received Date: 2015-07-01
  • Rev Recd Date: 2015-10-12
  • Available Online: 2021-01-23
  • Publish Date: 2016-03-30
  • The ash fusion characteristics, physical structure, chemical compositions and gasification reactivity of Zhundong coal (ZD) fly ash from fluidized bed gasification were explored by fusion point analyzer, X-ray fluorescence spectrometer (XRF), scanning electron microscopy (SEM), and thermo-gravimetric analyzer. The results show that the concentrations of minerals in ZD fly ash, such as SiO2, Fe2O3, Na2O, CaO, change greatly during gasification process, but the ash fusion temperature of ZD fly ash is similar to that of ZD. There is a wide particle-size distribution in ZD fly ash, which shows a significant bimodal distribution, and a large difference of elemental compositions for ZD fly ash of different particle size. The reactivity of ZD fly ash increases with the increase in gasification temperature. Compared with the ZD char from pyrolysis, the ZD fly ash has more advanced carbon crystalline structure, a larger surface area and is relatively rich in meso-pores and macro-pores, which results in a higher gasification reactivity.
  • loading
  • [1]
    陈川, 张守玉, 刘大海, 郭熙, 董爱霞, 熊绍武, 施大钟, 吕俊复.新疆高钠煤中钠的赋存形态及其对燃烧过程的影响[J].燃料化学学报, 2013, 41(7): 832-838. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18218.shtml

    CHEN Chuan, ZHANG Shou-yu, LIU Da-hai, GUO Xi, DONG Ai-xia, XIONG Shao-wu, SHI Da-zhong, LÜ Jun-fu. Existense form of sodium in high sodium coals from Xinjiang and its effect on combustion process[J]. J Fuel Chem Technol, 2013, 41(7): 832-838. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18218.shtml
    [2]
    董明钢.高钠煤对锅炉受热面结渣、沾污和腐蚀的影响及预防措施[J].热力发电, 2008, 37(9): 35-39. http://www.cnki.com.cn/Article/CJFDTOTAL-RLFD200809010.htm

    DONG Ming-gang. Influence of high-sodium coal upon slagging, contamination, and corrosion on the heating surface of boilers[J]. Therm Power Gener, 2008, 37(9): 35-39. http://www.cnki.com.cn/Article/CJFDTOTAL-RLFD200809010.htm
    [3]
    杨忠灿, 刘家利, 何红光.新疆准东煤特性研究及其锅炉选型[J].热力发电, 2010, 39(8): 38-40+44. http://www.cnki.com.cn/Article/CJFDTOTAL-RLFD201008013.htm

    YANG Zhong-can, LIU Jia-li, HE Hong-guang. Study on properties of Zhundong coal in Xinjiang region and type-selection for boilers burning this coal sort[J]. Therm Power Gener, 2010, 39(8): 38-40+44. http://www.cnki.com.cn/Article/CJFDTOTAL-RLFD201008013.htm
    [4]
    于强, 张健强.燃用高钠煤对锅炉受热面的影响[J].锅炉制造, 2012, (4): 4-6. http://www.cnki.com.cn/Article/CJFDTOTAL-GLZZ201204003.htm

    YU Qiang, ZHANG Jian-qiang. Effect of burning high-sodium coal on boiler heating surface[J]. Boiler Manuf, 2012, (4): 4-6. http://www.cnki.com.cn/Article/CJFDTOTAL-GLZZ201204003.htm
    [5]
    张守玉, 陈川, 施大钟, 吕俊复, 王健, 郭熙, 董爱霞, 熊绍武.高钠煤燃烧利用现状[J].中国电机工程学报, 2013, 33(5): 1-12+17. http://www.cnki.com.cn/Article/CJFDTOTAL-ZGDC201305001.htm

    ZHANG Shou-yu, CHEN Chuan, SHI Da-zhong, LÜ Jun-fu, WANG Jian, GUO Xi, DONG Ai-xia, XIONG Shao-wu. Situation of combustion utilization of high sodium coal[J]. Proc CSEE, 2013, 33(5): 1-12+7. http://www.cnki.com.cn/Article/CJFDTOTAL-ZGDC201305001.htm
    [6]
    LIN C L, PENG T H, WANG W J. Effect of particle size distribution on agglomeration/defluidization during fluidized bed combustion[J]. Powder Technol, 2011, 207(1/3): 290-295. https://www.researchgate.net/publication/251492155_Effect_of_particle_size_distribution_on_agglomerationdefluidization_during_fluidized_bed_combustion
    [7]
    李振珠, 马修卫, 李风海, 薛兆民, 黄戒介, 房倚天.煤气化飞灰特性的研究进展[J].应用化工, 2014, 43(10): 1891-1894+1898. http://www.cnki.com.cn/Article/CJFDTOTAL-SXHG201410042.htm

    LI Zhen-zhu, MA Xiu-wei, LI Feng-hai, XUE Zhao-min, HUANG Jie-jie, FANG Yi-tian. Review on fly ash characteristics from coal gasification[J]. Appl Chem Ind, 2014, 43(10): 1891-1894+1898. http://www.cnki.com.cn/Article/CJFDTOTAL-SXHG201410042.htm
    [8]
    MONDAL P, DANG G S, GARG M O. Syngas production through gasification and cleanup for downstream applications -recent developments[J]. Fuel Process Technol, 2011, 92(8): 1395-1410. doi: 10.1016/j.fuproc.2011.03.021
    [9]
    杨鑫, 黄戒介, 房倚天, 王洋.无烟煤流化床气化飞灰的结渣特性[J].燃料化学学报, 2013, 41(1): 1-8. doi: 10.1016/S1872-5813(13)60009-2

    YANG Xin, HUANG Jie-jie, FANG Yi-tian, WANG Yang. Slagging characteristics of fly ash from anthracite gasification in fludized bed[J]. J Fuel Chem Technol, 2013, 41(1): 1-8. doi: 10.1016/S1872-5813(13)60009-2
    [10]
    OBOIRIEN B O, ENGELBRECHT A D, NORTH B C, ERAMUS R M, FALCON R. Mineral-Char interaction during gasification of high-ash coals in fluidized-bed gasification[J]. Energy Fuels, 2011, 25(11): 5189-5199. doi: 10.1021/ef201056j
    [11]
    KELEBOPILE L, SUN R, LIAO J. Fly ash and coal char reactivity from Thermo-gravimetric (TGA) experiments[J]. Fuel Process Technol, 2011, 92(6): 1178-1186. doi: 10.1016/j.fuproc.2011.01.007
    [12]
    李风海, 李振珠, 黄戒介, 房倚天.神木煤流化床气化带出细粉的特性[J].燃料化学学报, 2014, 42(10): 1153-1159. doi: 10.1016/S1872-5813(14)60046-3

    LI Feng-hai, LI Zhen-zhu, HUANG Jie-jie, FANG Yi-tian. Characteristics of fine chars from fluidized bed gasification of Shenmu coal[J]. J Fuel Chem Technol, 2014, 42(10): 1153-1159. doi: 10.1016/S1872-5813(14)60046-3
    [13]
    GU J, WU S, WU Y, LI Y, GAO J. Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char[J]. Energy Fuels, 2008, 22(6): 4029-4033. doi: 10.1021/ef800527x
    [14]
    JING X, WANG Z, YU Z, ZHANG Q, LI C, FANG Y. Experimental and kinetic investigations of CO2 gasification of fine chars separated from a pilot-Scale fluidized-bed gasifier[J]. Energy Fuels, 2013, 27(5): 2422-2430. doi: 10.1021/ef4002296
    [15]
    蒋海波, 朱治平, 王月, 于旷世, 刘嘉鹏, 吕清刚.流化床煤气化试验研究[J].化学工程, 2014, 42(8): 60-64.

    JIANG Hai-bo, ZHU Zhi-ping, WANG Yue, YU Kuang-shi, LIU Jia-peng, LÜ Qing-gang. Coal gasification in fluidized bed[J]. Chem Eng, 2014, 42(8): 60-64.
    [16]
    范冬梅.低阶煤热解半焦的气化反应特性研究[D].北京:中国科学院研究生院(工程热物理研究所), 2013.

    FAN Dong-mei. Characteristics study on pyrolysis and gasification of low rank coals[D]. Beijing: University of Chinese Academy of Sciences (Institute of Engineering Thermophysics), 2013.
    [17]
    李伟, 李诗媛, 任强强, 吕清刚, 包绍麟.宁夏石沟驿煤气化残炭燃烧特性研究[J].煤炭转化, 2013, 36(3): 19-23. http://www.cnki.com.cn/Article/CJFDTOTAL-MTZH201303006.htm

    LI Wei, LI Shi-yuan, REN Qiang-qiang, LÜ Qing-gang, BAO Shao-lin. Combustion characteristics of residual carbon after gasification of coal from Ningxia Shigouyi[J]. Coal Convers, 2013, 36(3): 19-23. http://www.cnki.com.cn/Article/CJFDTOTAL-MTZH201303006.htm
    [18]
    刘敬, 王智化, 项飞鹏, 黄镇宇, 刘建忠, 周俊虎, 岑可法.准东煤中碱金属的赋存形式及其在燃烧过程中的迁移规律实验研究[J].燃料化学学报, 2014, 42(3): 316-322. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18373.shtml

    LIU Jing, WANG Zhi-hua, XIANG Fei-peng, HUANG Zhen-yu, LIU Jian-zhong, ZHOU Jun-hu, CEN Ke-fa. Models of occurence and transformation of alkali metals in Zhundong coal during combustion[J]. J Fuel Chem Technol, 2014, 42(3): 316-322. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18373.shtml
    [19]
    赵晓辉.基于矿物质赋存形态与转变过程的炉内灰渣沉积研究[D].杭州:浙江大学, 2007.

    ZHAO Xiao-hui. Study on ash deposition in boiler based on modes of occurrence and transformation of mineral matters[D]. Hangzhou: Zhejiang University, 2007.
    [20]
    LI F, HUANG J, FANG Y, WANG Y. Formation mechanism of slag during fluid-bed gasification of lignite[J]. Energy Fuels, 2011, 25: 273-280. doi: 10.1021/ef101268e
    [21]
    DAVISON R L, NATUSCH D F S, WALLACE J R, Evans C A.. Trace-elements in fly ash-dependence of concentration on particle-size[J]. Environ Sci Technol, 1974, 8(13): 1107-1113. doi: 10.1021/es60098a003
    [22]
    MANZOORI A R, AGARWAL P K. The fate of organically bound inorganic elements and sodium-chloride during fluidized-bed combustion of high sodium, high sulfur low rank coals[J]. Fuel, 1992, 71(5): 513-522. doi: 10.1016/0016-2361(92)90148-H
    [23]
    董倩, 张海霞, 朱治平.前处理方法对准东煤中钠含量测定的影响[J].洁净煤技术, 2015, 21(2): 82-86. http://www.cnki.com.cn/Article/CJFDTOTAL-JJMS201502020.htm

    DONG Qian, ZHANG Hai-xia, ZHU Zhi-ping. Influence of pretreatment on Na content analysis of Zhundong coal[J]. Clean Coal Technol, 2015, 21(2): 82-86 http://www.cnki.com.cn/Article/CJFDTOTAL-JJMS201502020.htm
    [24]
    WANG X, XU Z, WEI B, ZHANG L, YANG T, MIKULCIC H, DUIC N. The ash deposition mechanism in boilers burning Zhundong coal with high contents of sodium and calcium: A study from ash evaporating to condensing[J]. Appl Therm Eng, 2015, 80: 150-159. doi: 10.1016/j.applthermaleng.2015.01.051
    [25]
    TAKARADA T, TAMAI Y, TOMITA A. Reactivities of 34 coals under steam gasification[J]. Fuel, 1985, 64(10): 1438-1442. doi: 10.1016/0016-2361(85)90347-3
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (166) PDF downloads(22) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return