Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins

ZHANG Li; MENG Peng-tong; WANG Sen; QIN Zhang-feng; WANG Peng-fei; WANG Guo-fu; LI Jun-fen; DONG Mei; FAN Wei-bin; WANG Jian-guo

Volume 48 Issue 9

Sep. 2020

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2020 > 48(9): 1097-1104

ZHANG Li, MENG Peng-tong, WANG Sen, QIN Zhang-feng, WANG Peng-fei, WANG Guo-fu, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins[J]. Journal of Fuel Chemistry and Technology, 2020, 48(9): 1097-1104.

Citation:

ZHANG Li, MENG Peng-tong, WANG Sen, QIN Zhang-feng, WANG Peng-fei, WANG Guo-fu, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins[J]. Journal of Fuel Chemistry and Technology, 2020, 48(9): 1097-1104.

Citation:

ZHANG Li, MENG Peng-tong, WANG Sen, QIN Zhang-feng, WANG Peng-fei, WANG Guo-fu, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins[J]. Journal of Fuel Chemistry and Technology, 2020, 48(9): 1097-1104.

PDF( 7991 KB)

Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins

ZHANG Li^{1, 2},
MENG Peng-tong^{1, 2},
WANG Sen¹,
QIN Zhang-feng^{1
,
,},
WANG Peng-fei¹,
WANG Guo-fu¹,
LI Jun-fen^{1
,
,},
DONG Mei¹,
FAN Wei-bin¹,
WANG Jian-guo^{2
,
,}

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds:

the National Natural Science Foundation of China 21991092

the National Natural Science Foundation of China U1910203

the National Natural Science Foundation of China U1862101

the National Natural Science Foundation of China 21773281

the National Natural Science Foundation of China 21802157

the Strategic Priority Research Program of Chinese Academy of Sciences XDA21020500

Natural Science Foundation of Shanxi Province of China 201901D211581

More Information

Corresponding author: E-mail: qzhf@sxicc.ac.cn(QIN Zhang-feng); E-mail: lijunfen@sxicc.ac.cn(LI Jun-fen); E-mail: iccjgw@sxicc.ac.cn(WANG Jian-guo)
Received Date: 2020-06-15
Rev Recd Date: 2020-08-08

Available Online: 2021-01-23

Publish Date: 2020-09-10

Abstract

Abstract

RUB-13 zeolites were synthesized by hydrothermal method. The effect of organic structure-directing agent (OSDA), silica source, crystallization temperature and Si/H₂O ratio on the crystal structure was investigated and the catalytic performance of H-RUB-13 in the conversion of methanol to olefins (MTO) was evaluated. The results indicate that with 1, 2, 2, 6, 6-pentamethylpiperidine (PMP) as OSDA and fumed silica as silica source, pure and highly crystalline RUB-13 zeolites with a Si/Al ratio of 100 or 200 can be successfully synthesized by crystallization at 170 ℃, with a H₂O/Si ratio of 100 or 80 in the synthesis gel, respectively. The crystals of the synthesized RUB-13 zeolites display a thin rod-like morphology. As a catalyst in MTO, the high-silica H-Al-B-RUB-13 (Si/Al=200) zeolite exhibits unprecedentedly high selectivity to light olefins at 400 ℃ (54.5% to propene and 97.8% to C_2-5⁼), much better than the traditional H-SAPO-34 and H-ZSM-5 zeolites under similar conditions.
- RUB-13 zeolite,
- hydrothermal synthesis,
- methanol to olefins (MTO),
- catalytic performance

FullText(HTML)

References(19)

References

[1]	CUNDY C S, COX P A. The hydrothermal synthesis of zeolites:History and development from the earliest days to the present time[J]. Chem Rev, 2003, 103(3):663-702. doi: 10.1021/cr020060i
[2]	CORMA A. State of the art and future challenges of zeolites as catalysts[J]. J Catal, 2003, 216(1/2):298-312. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=c3a0d63140c3dc2c29aa936cf6b1e489
[3]	慕旭宏, 王殿中, 王永睿, 林民, 程时标, 舒兴田.纳米分子筛在炼油和石油化工中的应用[J].催化学报, 2013, 34(1):69-79. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cuihuaxb201301007 MU Xu-hong, WANG Dian-zhong, WANG Yong-rui, LIN Min, CHENG Shi-biao, SHU Xing-tian. Nanosized molecular sieves as petroleum refining and petrochemical catalysts[J]. Chin J Catal, 2013, 34(1):69-79. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cuihuaxb201301007
[4]	程志林, 晁自胜, 万惠霖.气体分离分子筛膜[J].化学进展, 2004, 16(1):61-67. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hxjz200401010 CHENG Zhi-lin, CHAO Zi-sheng, WAN Hui-lin. Progress in the research of zeolite membrane on gas separation[J]. Prog Chem, 2004, 16(1):61-67. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hxjz200401010
[5]	ZHU Q, KONDO J N, OHNUMA R, KUBOTA Y, YAMAGUCHI M, TATSUMI T. The study of methanol-to-olefin over proton type aluminosilicate CHA zeolites[J]. Microporous Mesoporous Mater, 2008, 112(1/3):153-161. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cc7d73c543f52e0afd687143c7a618d7
[6]	ZHU Q, HINODE M, YOKOI T, KONDO J N, KONDO Y, TATSUMI T. Methanol-to-olefin over gallosilicate analogues of chabazite zeolite[J]. Microporous Mesoporous Mater, 2008, 116(1/3):253-257. http://www.sciencedirect.com/science/article/pii/S138718110800187X
[7]	LIANG J, LI H, ZHAO S, GUO W, WANG R, YING M. Characteristics and performance of SAPO-34 catalyst for methanol-to-olefin conversion[J]. Appl Catal, 1990, 64:31-40. doi: 10.1016/S0166-9834(00)81551-1
[8]	ZHU Q, KONDO J N, TATSUMI T, INAGAKI S, OHNUMA R, KUBOTA Y, SHIMODAIRA Y, DOMEN K. A comparative study of methanol to olefin over CHA and MTF zeolites[J]. J Phys Chem C, 2007, 111(14):5409-5415. doi: 10.1021/jp063172c
[9]	唐君琴, 叶丽萍, 应卫勇, 房鼎业.硅铝比对SAPO-34催化剂在甲醇制烯烃反应中催化性能的影响[J].石油化工, 2010, 39(1):22-27. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syhg201001005 TANG Jun-qin, YE Li-ping, YING Wei-yong, FANG Ding-ye. Performances of SAPO-34 catalysts with different ratios of Si to Al in methanol-to-olefins[J]. Petrochem Technol, 2010, 39(1):22-27. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=syhg201001005
[10]	PARK J W, LEE J Y, KIM K S, HONG S B, SEO G. Effects of cage shape and size of 8-membered ring molecular sieves on their deactivation in methanol-to-olefin (MTO) reactions[J]. Appl Catal A:Gen, 2008, 339(1):36-44. doi: 10.1016/j.apcata.2008.01.005
[11]	IVANOVA S, LEBRUN C, VANHAECKE E, PHAM-HUU C, LOUIS B. Influence of the zeolite synthesis route on its catalytic properties in the methanol to olefin reaction[J]. J Catal, 2009, 265(1):1-7. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=5719ec11f11a92d00cea5543a3d3ff31
[12]	BLEKEN F L, CHAVAN S, OLSBYE U, BOLTZ M, OCAMPO F, LOUIS B. Conversion of methanol into light olefins over ZSM-5 zeolite:Strategy to enhance propene selectivity[J]. Appl Catal A:Gen, 2012, 447:178-185. http://www.sciencedirect.com/science/article/pii/S0926860X12006187
[13]	YOKOI T, YOSHIOKA M, IMAI H, TATSUMI T. Diversification of RTH-type zeolite and its catalytic application[J]. Angew Chem Int Ed, 2009, 48(52):9884-9887. doi: 10.1002/anie.200905214
[14]	YOSHIOKA M, YOKOI T, LIU M, IMAI H, INAGAKI S, TATSUMI T. Preparation of RTH-type zeolites with the amount and/or kind of organic structure-directing agents (OSDA):Are OSDAs indispensable for the crystallization?[J]. Microporous Mesoporous Mater, 2012, 153:70-78. doi: 10.1016/j.micromeso.2011.12.024
[15]	LIU M, YOKOI T, YOSHIOKA M, IMAI H, KONDO J N, TATSUMI T. Differences in Al distribution and acidic properties between RTH-type zeolites synthesized with OSDAs and without OSDAs[J]. Phys Chem Chem Phys, 2014, 16(9):4155-4164. doi: 10.1039/c3cp54297a
[16]	ZHANG L, WANG S, SHI D, QIN Z, WANG P, WANG G, LI J, DONG M, FAN W, WANG J. Methanol to olefins over H-RUB-13 zeolite:Regulation of framework aluminum siting and acid density and their relationship to the catalytic performance[J]. Catal Sci Technol, 2020, 10(6):1835-1847. doi: 10.1039/C9CY02419K
[17]	贾艳萍, 马姣, 张兰河, 董长青, 王孝强.多孔二氧化硅材料的应用进展[J].硅酸盐通报, 2014, 33(12):3206-3212. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gsytb201412026 JIA Yan-ping, MA Jiao, ZHANG Lan-he, DONG Chang-qing, WANG Xiao-qiang. Application progress on porous silica material[J]. Bull. Chin Ceram Soc, 2014, 33(12):3206-3212. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gsytb201412026
[18]	LANDRY C C, TOLBERT S H, GALLIS K W, MONNIER A, STUCKY G D, NORBY P, HANSON J C. Phase transformations in mesostructured silica/surfactant composites. Mechanisms for change and applications to materials synthesis[J]. Chem Mater, 2001, 13(5):1600-1608. doi: 10.1021/cm000373z
[19]	VORTMANN S, MARLER B, GIES H, DANIELS P. Synthesis and crystal structure of the new borosilicate zeolite RUB-13[J]. Microporous Mesoporous Mater, 1995, 4(2/3):111-121. http://www.sciencedirect.com/science/article/pii/092765139400090I