Preparation of Ni<sub>2</sub>P/Zr-MCM-41 catalyst and its performance in the hydrodeoxygenation of Jatropha curcas oil

LUO Nan; CAO Yang; LI Jin; GUO Wei; ZHAO Zi-wei

Volume 44 Issue 1

Jan. 2016

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LUO Nan, CAO Yang, LI Jin, GUO Wei, ZHAO Zi-wei. Preparation of Ni2P/Zr-MCM-41 catalyst and its performance in the hydrodeoxygenation of Jatropha curcas oil[J]. Journal of Fuel Chemistry and Technology, 2016, 44(1): 76-83.

Citation:

LUO Nan, CAO Yang, LI Jin, GUO Wei, ZHAO Zi-wei. Preparation of Ni₂P/Zr-MCM-41 catalyst and its performance in the hydrodeoxygenation of Jatropha curcas oil[J]. Journal of Fuel Chemistry and Technology, 2016, 44(1): 76-83.

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Preparation of Ni₂P/Zr-MCM-41 catalyst and its performance in the hydrodeoxygenation of Jatropha curcas oil

School of Material and Chemical Engineering, Hainan University, Haikou 570228, China

Funds:

The project was supported by Hainan Key Project of China ZDXM2015116

The project was supported by Hainan Key Project of China ZDXM20120072

Hainan Natural Science Foundation of China 20152028

More Information

Corresponding author: LI Jin, Tel:0898-66279226, E-mail:316800681@qq.com
Received Date: 2015-09-02
Rev Recd Date: 2015-11-19

Available Online: 2022-03-23

Publish Date: 2016-01-01

Abstract

Abstract

With hydrothermally synthesized MCM-41 and Zr-MCM-41 as the supports, Ni₂P/Zr-MCM-41 catalysts were prepared by co-impregnation with Ni (NO₃)₂ and (NH₄)₂HPO₄ solution, calcination, reduction with H₂ and subsequent passivation. The Ni₂P/Zr-MCM-41 catalysts were characterized by XRD, Py-IR, TEM, XPS, N₂ physisorption and CO chemisorption; their catalytic performance in the hydrodeoxygenation (HDO) of Jatropha curcas oil to produce the second-generation biodiesel was investigated in an autoclave. The results indicated that Ni₂P can be well dispersed on Zr-MCM-41 with a loading of 20% by reduction at 650 ℃ from the phosphate precursors. The Ni₂P/Zr-MCM-41 catalyst exhibit excellent performance in the HDO of Jatropha curcas oil. Over the Ni₂P/Zr-MCM-41 catalyst with a Ni₂P loading of 20%, the HDO conversion achieves 93.90% and the fraction of linear paraffins in the product oil reaches 85.36%, in which diesel fraction (C_15~20) may exceed 61.90%; the components of oil generated through HDO are similar to those of fossil diesel.
- Ni₂P,
- Zr-MCM-41,
- hydrodeoxygenation,
- Jatropha curcas oil

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References(22)

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