Preparation of metal-organic frameworks Cu3(BTC)2 with amino-functionalization for CO2 adsorption

LU Xue-ting; PU Yan-feng; LI Lei; ZHAO Ning; WANG Feng; XIAO Fu-kui

Volume 47 Issue 3

Mar. 2019

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Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(3): 338-343

LU Xue-ting, PU Yan-feng, LI Lei, ZHAO Ning, WANG Feng, XIAO Fu-kui. Preparation of metal-organic frameworks Cu3(BTC)2 with amino-functionalization for CO2 adsorption[J]. Journal of Fuel Chemistry and Technology, 2019, 47(3): 338-343.

Citation:

LU Xue-ting, PU Yan-feng, LI Lei, ZHAO Ning, WANG Feng, XIAO Fu-kui. Preparation of metal-organic frameworks Cu₃(BTC)₂ with amino-functionalization for CO₂ adsorption[J]. Journal of Fuel Chemistry and Technology, 2019, 47(3): 338-343.

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Preparation of metal-organic frameworks Cu₃(BTC)₂ with amino-functionalization for CO₂ adsorption

LU Xue-ting^{1, 2},
PU Yan-feng¹,
LI Lei¹,
ZHAO Ning^{1
,
,},
WANG Feng^{1
,
,},
XIAO Fu-kui¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds:

The project was supported by the National Natural Science Foundation of China 21306217

The project was supported by the National Natural Science Foundation of China 21776294

Coal-Based Science and Technology Project of Shanxi Province MD2014-09

Natural Science Foundation of Shanxi Province 201601D102006

Natural Science Foundation of Shanxi Province 201801D121070

More Information

Corresponding author: ZHAO Ning, E-mail: zhaoning@sxicc.ac.cn; WANG Feng, E-mail: wangf@sxicc.ac.cn
Received Date: 2018-11-08
Rev Recd Date: 2018-12-24

Available Online: 2021-01-23

Publish Date: 2019-03-10

Abstract

Abstract

The metal-organic framework of Cu₃(NH₂BTC)₂ was synthesized by solvothermal method with the prepared grafted amine-based trimesic acid as organic ligand. The synthesized adsorbent was characterized by XRD, N₂ adsorption-desorption, thermogravimetry, FT-IR and in-situ FT-IR. The performance of the CO₂ adsorption was studied by the breakthrough curve based on the fixed-bed reactor. The results showed that the amine groups had been successfully grafted into the skeleton of Cu₃(BTC)₂. The CO₂ adsorption capacity of Cu₃(NH₂BTC)₂ was improved to 1.41 mmol/g at 10 kPa and 50 ℃. The improvement of CO₂ uptake might due to the effect of both the physical and chemical adsorption of CO₂.
- amino-functionalized,
- Cu₃(BTC)₂,
- CO₂ adsorption

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References(27)

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