Volume 44 Issue 5
May  2016
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ZHANG Li-qiang, LI Kai, ZHU Xi-feng. Two-step pyrolysis characteristics of bean stalks[J]. Journal of Fuel Chemistry and Technology, 2016, 44(5): 534-539.
Citation: ZHANG Li-qiang, LI Kai, ZHU Xi-feng. Two-step pyrolysis characteristics of bean stalks[J]. Journal of Fuel Chemistry and Technology, 2016, 44(5): 534-539.

Two-step pyrolysis characteristics of bean stalks

Funds:

the Major State Basic Research Development Program of China 973 program

the Major State Basic Research Development Program of China 2013CB228103

the Key Research Program of the Chinese Academy of Sciences KGZD-EW-304-3

  • Received Date: 2015-12-21
  • Rev Recd Date: 2016-02-22
  • Available Online: 2021-01-23
  • Publish Date: 2016-05-10
  • Two-step pyrolysis of soybean stalk was investigated using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The results indicate that with the increase of the first-step pyrolysis temperature (t1), the total peak area of the first-step products becomes higher. However, for the second-step, the total peak area decreases gradually with the increase of t1. The products in the first-step pyrolysis have higher contents of acids, ketones and furans when t1 is 400 or 450 ℃. This is because that the products are originated from cellulose and hemicellulose. The content of hydrocarbon products in the second-step is more than 20% when t1 is 450 or 500 ℃. With two-step pyrolysis some products with high content can be obtained in the first or second step, respectively, such as acetic acid, furfural, guaiacol, methylbenzene and benzene etc., thus preliminarily achieving the selective pyrolysis of biomass.
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