负载金属对MoO3-TiO2光催化剂结构与催化性能的影响

M/MoO3-TiO2(M=Pd, Cu, Ni, Ag) photocatalysts were prepared by sol-gel and impregnation-reaction method. The surface structure, adsorption property, photo absorption performance and photo catalytic performance of M/MoO3-TiO2 catalysts were characterized by XRD, TPR, IR, TPD, UV-VisDRS and photoreaction techniques. The experiment results showed that the supported metallic M (M=Pd, Cu) on coupled semiconductor MoO3-TiO2 restrains TiO2 transformation from anatase to rutile and improves the transformation from the tetrahedrally coordinated Mo oxide species to the octahedrally coordinated Mo oxide species. The blue shifting of photo absorption edge and increasing of the photo absorption capacity to visible light were observed clearly after the addition of metallic M (M=Pd, Cu, Ag) on the surface of MoO3-TiO2. The photo absorption decreases in the order of Pd/MoO3-TiO2, Cu/MoO3-TiO2, Ag/MoO3-TiO2 and Ni/MoO3-TiO2. It can be concluded that the adsorption of CO2 on Pd/MoO3-TiO2 is very strong, and its desorption temperature of horizontal adsorption state increases, thus its photo quantum efficiency is lower than that of Cu/MoO3-TiO2, on which desorption temperature for both CO2 and C3H6 is about the same. Loaded metallic Cu realizes “photo-surface-thermal” synergistic effects and improves photo quantum yield.