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原子层沉积技术调控分子筛基催化剂研究进展

魏丽 王树元 闫梦霞 朱地 陶智超 徐丹

魏丽, 王树元, 闫梦霞, 朱地, 陶智超, 徐丹. 原子层沉积技术调控分子筛基催化剂研究进展[J]. 燃料化学学报(中英文), 2024, 52(2): 285-292. doi: 10.19906/j.cnki.JFCT.2023056
引用本文: 魏丽, 王树元, 闫梦霞, 朱地, 陶智超, 徐丹. 原子层沉积技术调控分子筛基催化剂研究进展[J]. 燃料化学学报(中英文), 2024, 52(2): 285-292. doi: 10.19906/j.cnki.JFCT.2023056
WEI Li, WANG Shuyuan, YAN Mengxia, ZHU Di, TAO Zhichao, XU Dan. Recent progress in regulating of zeolite-based catalysts by atomic layer deposition technology[J]. Journal of Fuel Chemistry and Technology, 2024, 52(2): 285-292. doi: 10.19906/j.cnki.JFCT.2023056
Citation: WEI Li, WANG Shuyuan, YAN Mengxia, ZHU Di, TAO Zhichao, XU Dan. Recent progress in regulating of zeolite-based catalysts by atomic layer deposition technology[J]. Journal of Fuel Chemistry and Technology, 2024, 52(2): 285-292. doi: 10.19906/j.cnki.JFCT.2023056

原子层沉积技术调控分子筛基催化剂研究进展

doi: 10.19906/j.cnki.JFCT.2023056
基金项目: 国家自然科学基金(22002064),山东省自然科学基金(ZR2020QB050,ZR2021MB046),山东省青创计划(2021KJ033),济南市“高校20条”项目(202228036)和科教产-强基计划(2022PY019)资助
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    通讯作者:

    Tel: + 86-0531-82605937, E-mail: syw.fe@outlook.com

    xudan07@qlu.edu.cn

  • 中图分类号: O643.36

Recent progress in regulating of zeolite-based catalysts by atomic layer deposition technology

Funds: The project was supported by National Natural Science Foundation of China (22002064),Shandong Provincial Natural Science Foundation (ZR2020QB050,ZR2021MB046), Qingchuang Science and Technology Support Project of Shandong Colleges and Universities (2021KJ033), Plan for the 20 New Colleges and Universities in Jinan (202228036), Plan for Integration of Science, Education and Industry (2022PY019)
  • 摘要: 分子筛基催化剂在多相催化研究领域具有重要的应用,但调控活性中心粒子的结构及其在分子筛上的空间位置仍比较困难,是科研界和工业界共同面临的巨大挑战。原子层沉积(ALD)是一种先进的薄膜沉积技术,利用其自限制生长优势,可在原子级别实现对金属粒子生长过程的精准调控。本工作综述了ALD技术在制备分子筛基催化剂方面的应用,主要包括利用ALD技术控制活性位点在分子筛上的生长落位、修饰分子筛骨架结构以及选择性沉积膜调变分子筛表面结构。利用ALD技术设计和调控活性组分结构促进了分子筛基催化剂的发展,但由于分子筛孔道结构复杂且存在缺陷位,因此,ALD技术在分子筛基催化剂的设计调控及大规模应用方面仍具有挑战性,也是今后研究工作的重点。
  • FIG. 2935.  FIG. 2935.

    FIG. 2935.  FIG. 2935.

    图  1  Zn在ZSM-5分子筛上的沉积过程示意图[7]

    Figure  1  The deposition model of Zn on ZSM-5 zeolite[7](with permission from Elsevier)

    图  2  MeCpPtMe3分子在KL分子筛内的吸附-扩散行为[18]

    Figure  2  The energetics of diffusion progress of the MeCpPtMe3 through a KL zeolite channel:(a) the energetics of MeCpPtMe3 in the inner and outer surfaces of KL zeolite, (b) diffusion energetics of MeCpPtMe3 into/between KL zeolite cages[18](with permission from Royal Society of Chemistry)

    图  3  多级孔KL分子筛的合成及ALD调控Pt团簇空间分布的机理过程[21]

    Figure  3  Formation mechanism of hierarchical porous KL zeolite and the spatial locations of Pt clusters based on the ALD deposition mechanism [21](with permission from Elsevier)

    图  4  在KL分子筛上利用ALD调控PtFe-n/KL催化剂合成的示意图[6]

    Figure  4  Schematic diagram of the procedure for the synthesis of PtFe-n/KL catalysts via ALD on the KL zeolite[6](with permission from American Chemical Society)

    图  5  在BaKL分子筛上制备亚纳米Pt团簇的过程示意图[34]

    Figure  5  Illustration of the preparation of sub-nanometric Pt on the BaKL[34](with permission from Elsevier)

    图  6  (a)−(f) Pt/KL和Pt/BKL催化剂的HAADF-TEM图及尺寸分布;(g)、(h)n-C7芳构化活性评价[34]

    Figure  6  (a)−(f) High angle annular dark field scanning transmission electron microscopy (HAADF-STEM) image of Pt/KL and Pt/BKL catalysts with size distribution of Pt; (g), (h) Catalytic performance on n-C7 aromatization[34](with permission from Elsevier)

    图  7  ALD技术调控Pt-Zn沉积KL分子筛的合成策略[35]

    Figure  7  Synthetic strategy of Pt-Zn deposited KL catalyst by ALD method[35](with permission from Elsevier)

    图  8  利用ALD调控甲醇沉积于Y分子筛外表面、Pt沉积于Y分子筛孔道内以制备Pt/KYCx催化剂的示意图[43]

    Figure  8  Schematic illustration of preparing Pt/KYCx catalysts via ALD with methanol located on the outer surface and Pt inside channels of Y zeolite(with permission from Elsevier)[43]

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出版历程
  • 收稿日期:  2023-05-31
  • 修回日期:  2023-07-10
  • 录用日期:  2023-07-13
  • 网络出版日期:  2023-09-01
  • 刊出日期:  2024-02-02

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