郑朝阳, 解新安, 陶红秀, 郑璐丝, 李雁. 亚/超临界乙醇液化秸秆纤维素解聚反应研究与机理初探[J]. 燃料化学学报(中英文), 2012, 40(05): 526-532.
引用本文: 郑朝阳, 解新安, 陶红秀, 郑璐丝, 李雁. 亚/超临界乙醇液化秸秆纤维素解聚反应研究与机理初探[J]. 燃料化学学报(中英文), 2012, 40(05): 526-532.
ZHENG Chao-yang, XIE Xin-an, TAO Hong-xiu, ZHENG Lu-si, LI Yan. Depolymerization of stalk cellulose during its liquefaction in sub- and supercritical ethanol[J]. Journal of Fuel Chemistry and Technology, 2012, 40(05): 526-532.
Citation: ZHENG Chao-yang, XIE Xin-an, TAO Hong-xiu, ZHENG Lu-si, LI Yan. Depolymerization of stalk cellulose during its liquefaction in sub- and supercritical ethanol[J]. Journal of Fuel Chemistry and Technology, 2012, 40(05): 526-532.

亚/超临界乙醇液化秸秆纤维素解聚反应研究与机理初探

Depolymerization of stalk cellulose during its liquefaction in sub- and supercritical ethanol

  • 摘要: 利用间歇式高压反应釜,在反应温度200~330 ℃、乙醇用量0~150 mL条件下,考察了亚/超临界乙醇直接液化秸秆纤维素的解聚行为,并初步探讨了其液化机理。结果表明,反应温度、乙醇用量和反应停留时间对秸秆纤维素的液化均有显著影响,反应温度由200 ℃升高至330 ℃,重油和气体收率分别增加了12.55%、28.83%;乙醇用量增加,反应压力随之升高,乙醇进入超临界状态,残渣和气体收率相比单纯热裂解分别降低11.10%和8.44%。通过GC/MS、FT-IR分析生物油组分和残渣特性,表明秸秆纤维素在亚/超临界乙醇中断键裂解,且酮类和乙酯类化合物是生物油的主要成分。

     

    Abstract: Direct liquefaction of cornstalk cellulose in sub-/super-critical ethanol was investigated with a batch reactor at 200~330 ℃ and an initial usage of ethanol varying from 0 to 150 mL. The results show that the reaction temperature, ethanol quantity and retention time significantly influence the direct liquefaction of cornstalk cellulose. The yields of heavy oil and gases increase by 12.55% and 28.83% respectively, depending on reaction temperature from 200 to 330 ℃. The reaction pressure increases with the increment of ethanol, and the yield of residues and gases reduces by 11.10% and 8.44% in supercritical ethanol compared with that from thermal cracking without ethanol. The FT-IR analyses for residues and GC/MS measurements for the oils reveal that cornstalk cellulose was liquefied through deploymerization in supercritical ethanol, and the main components of oils are ketone and ethyl ester and their derivatives.

     

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