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生物质基糠醛化学催化制备含氮化合物的研究进展

陈佳月 李克明 黄耀兵 陆强

陈佳月, 李克明, 黄耀兵, 陆强. 生物质基糠醛化学催化制备含氮化合物的研究进展[J]. 燃料化学学报(中英文). doi: 10.19906/j.cnki.JFCT.2024007
引用本文: 陈佳月, 李克明, 黄耀兵, 陆强. 生物质基糠醛化学催化制备含氮化合物的研究进展[J]. 燃料化学学报(中英文). doi: 10.19906/j.cnki.JFCT.2024007
CHEN Jiayue, LI Keming, HUANG Yaobing, LU Qiang. Research progress of chemical catalysis for biomass-based furfural to nitrogen-containing compounds[J]. Journal of Fuel Chemistry and Technology. doi: 10.19906/j.cnki.JFCT.2024007
Citation: CHEN Jiayue, LI Keming, HUANG Yaobing, LU Qiang. Research progress of chemical catalysis for biomass-based furfural to nitrogen-containing compounds[J]. Journal of Fuel Chemistry and Technology. doi: 10.19906/j.cnki.JFCT.2024007

生物质基糠醛化学催化制备含氮化合物的研究进展

doi: 10.19906/j.cnki.JFCT.2024007
基金项目: 国家自然科学基金 (52276189, 51821004)资助
详细信息
    通讯作者:

    E-mail: hyb123@mail.ustc.edu.cn

    qianglu@mail.ustc.edu.cn

  • 中图分类号: TK6

Research progress of chemical catalysis for biomass-based furfural to nitrogen-containing compounds

Funds: The project was supported by National Natural Science Foundation of China (52276189, 51821004).
  • 摘要: 糠醛作为最有潜力的生物质基平台化合物之一,可通过化学催化转化为一系列高附加值的化学品和燃料。其中,含氮化合物具有广泛的生物活性,常用于合成药物分子和生物塑料等功能性材料。糠醛通过还原胺化、氨氧化、氧化偶联等过程,可以合成不同类型的含氮化合物,具有巨大的研究前景和应用潜力。本论文综述了近年来以糠醛为原料合成各种高值含氮化合物的研究进展,包括胺类化合物(伯胺、仲胺和叔胺)、腈类化合物、酰胺类化合物和杂环类化合物(苯并杂环类、噻唑类、吡咯、吲哚、哌啶和吡啶等)。重点关注合成方法、催化剂类型、反应路径和反应机理,同时分析了催化剂和氮源对产物分布的影响。该综述为今后生物质基糠醛转化为含氮化合物的研究提供了一些基础信息,为发展更多高效的糠醛催化转化体系提供依据和系统性知识。
  • 图  1  以糠醛为原料合成含氮化合物

    Figure  1  The synthesis of nitrogen-containing compounds from furfural

    图  2  以NH3为氮源,糠醛制备糠胺的合成路径

    Figure  2  The synthetic pathway of furfural to furfural amine utilizing NH3 as the nitrogen source

    图  3  以N2H4·H2O为氮源,糠醛制备糠胺的合成路径

    Figure  3  The synthetic pathway of furfural to furfural amine utilizing N2H4·H2O as the nitrogen source

    图  4  糠醛先与甲基异丁酮缩醛,再还原胺化转化为呋喃胺类化合物

    Figure  4  Furfural is first combined with methyl isobutyl ketone by aldol condensation, followed by amination reduction to produce furan amine compounds

    图  5  以NH3为氮源,糠醛制备2-氰基呋喃的合成路径

    Figure  5  The synthetic pathway of furfural to furan-2-carbonitrile utilizing NH3 as the nitrogen source

    图  6  以羟胺为氮源,糠醛制备糠酰胺的合成路径

    Figure  6  The synthetic pathway of furfural to 2-furamide utilizing hydroxylamine as the nitrogen source

    图  7  糠醛合成2-(呋喃-2-基)苯并[D]咪唑的反应路径

    Figure  7  The synthetic pathway of 2-(furan-2-yl)-1H-benzo[d]imidazole from furfural

    图  8  糠醛合成2-糠基噻唑-4-羧酸甲酯的路径

    Figure  8  The synthetic pathway of furfural to 2-furylthiazole-4-carboxylic acid methyl ester

    图  9  糠醛合成吡咯和吲哚的路径

    Figure  9  The synthetic pathway of furfural to pyrrole and indole

    图  10  糠醛合成哌啶、吡啶和3-羟基吡啶的路径

    Figure  10  The synthetic pathway of furfural to piperidine, pyridine and 3-hydroxypyridine.

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出版历程
  • 收稿日期:  2024-01-18
  • 修回日期:  2024-03-03
  • 录用日期:  2024-03-06
  • 网络出版日期:  2024-04-02

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