Abstract:
The oxidation of alcohols is a significant chemical reaction, and the efficient oxidation of alcohols over heterogeneous catalysts using oxygen as oxidant has attracted much attention in recent years. Among them, Pd/CeO
2 exhibits excellent alcohol oxidation performance. However, the structure-activity relationship between the catalyst’s structure and its catalytic performance for alcohol oxidation is still not clearly understood. This study involved the preparation of CeO
2 nanosheets with different concentrations of surface oxygen vacancies (Ov) and their subsequent loading with Pd to explore their catalytic performance for alcohol oxidation. The findings obtained through XPS, Raman, and XAS indicated a positive correlation between the surface Ov concentration of CeO
2 as well as the ratio of Pd
2+ fraction. The alcohol oxidation results and structure-performance relationship studies showed that there was a good linear relationship between the Pd
2+ ratio as well as the surface Ce
3+ concentration and the TOF of benzyl alcohol oxidation reaction, respectively. And the interfacial site (Pd–O–Ce) formed by Pd and CeO
2 was the main catalytic site for this type of alcohol oxidation catalysts. This study contributes to the understanding of the catalytic role of interfacial sites in metal and oxide support for the development of better alcohol oxidation catalysts.