过滤介质对低阶煤热解焦油气反应行为的影响研究

Effect of filter media on gaseous tar reaction during low-rank coal pyrolysis

  • 摘要: 低阶煤热解焦油气通过颗粒床过滤器除尘时,过滤介质在一定程度上会影响热解焦油气的反应行为。本研究采用下行床热解反应器考察了陶瓷球(CB)、膨胀珍珠岩(EP)、活性炭(AC)和γ-Al2O3四种颗粒床过滤介质对淖毛湖长焰煤热解焦油气反应性的影响,结果表明,热解产物的分布、组成及其积炭行为受过滤介质种类的影响显著。CB、EP相对惰性,因延长了焦油气的停留时间,加剧了裂解和缩聚反应,焦油产率减小、沥青含量升高,热解气、热解水及积炭产率增加, 但焦油积炭量和化学组成没有明显变化;AC、γ-Al2O3具有较强的催化裂解活性,可明显降低焦油沥青含量和积炭量,但会使焦油向热解气、热解水及积炭转化,导致焦油产率显著下降。同时,AC、γ-Al2O3可裂解焦油气中部分含氧化合物和含氮、硫杂环化合物,使其转化为芳香烃。

     

    Abstract: When a granular bed filter is used for the dust removal of hot gas containing tar from low-rank coal pyrolysis, the filter media will affect the reaction behavior of gaseous tar to a certain extent. Four granular bed filter media including ceramic ball (CB), expanded perlite (EP), activated carbon (AC) and γ-Al2O3, were selected to investigate their influence on the gaseous tar reaction during Naomaohu long-flame coal pyrolysis in a downer-bed pyrolysis reactor. The results indicate that the distribution and compositions of pyrolysis products and the coke deposition behavior are significantly affected by the filter media. The inert CB and EP increase the residence time of gaseous tar, which intensifies the cracking and polycondensation reactions of gaseous tar, resulting in a reduction in the tar yield and an increase in the gas, water and coke yield. In the meantime, the pitch content in tar is increased due to the polycondensation reactions of gaseous tar, while the chemical composition of tar and the amount of coke in tar have less change. The AC and γ-Al2O3, which have a strong catalytic cracking action, reduce the pitch content and the amount of coke in tar. Also, partial gaseous tar is transformed into gas, water and coke, resulting in an obvious reduction in the tar yield. Also, AC and γ-Al2O3 can crack some oxygen-containing compounds and nitrogen-containing or sulfur-containing heterocycles in the gaseous tar into aromatics.

     

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