离子液体在光/电催化还原CO2中的作用

Role of ionic liquids in photo/electrocatalytic reduction of CO2

  • 摘要: 将CO2还原为能源燃料是缓解能源危机和温室效应的一种有效途径。近年来,世界各国学者针对CO2的光/电催化还原技术开展了广泛的研究,但光/电催化还原CO2仍然存在可见光响应能力低、光生电子和空穴的复合率高、CO2的吸附量小、产物的选择性差等问题,制约了该领域的快速发展。离子液体(ILs)作为一种新型绿色溶剂,热稳定性高,对CO2吸附性强,在光/电催化还原CO2反应中既可用作反应介质,又可起到助催化作用,因此,研究广泛。本研究对近年来离子液体(ILs)在光/电催化还原CO2中的研究现状和作用进行分析和综述,并对离子液体(ILs)在该领域的发展前景进行展望。

     

    Abstract: Reducing CO2 into energy fuel is an effective way to alleviate the energy crisis and greenhouse effect. In recent years, domestic and foreign scholar have carried out extensive research on the photo(electro)catalytic reduction of CO2. However, the photo(electro)catalytic reduction of CO2 still has some problems, such as low visible light response, high recombination rate of photo-generated electrons and holes, small CO2 adsorption and poor selectivity of products, which restrict the rapid development of this field. As a new type of green solvent, ionic liquids (ILs) have high thermal stability and strong CO2 adsorption. They can be used as reaction medium or co-catalyst in the photo(electro)catalytic reduction of CO2 chemical reactions, so they have been widely studied. In this paper, the research status and roles of ionic liquids in photo(electro)catalytic reduction of CO2 in recent years are analyzed and reviewed, and the development prospect of ILs in this field is prospected.

     

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