CO2电还原生成甲酸盐机理及催化剂研究

Research on mechanism and catalysts of CO2 electroreduction to formate

  • 摘要: 本工作综述了近五年来CO2电催化还原生成甲酸盐领域取得的最新进展。介绍了CO2电还原生成甲酸盐的反应机理,以及该过程所使用的催化剂的类型,包括金属催化剂、原子分散催化剂、金属氧化物催化剂、炭材料及复合材料催化剂。从催化剂、电解液、反应气氛和电解池等多角度详细分析了影响产物选择性、催化活性和稳定性的主要因素。针对目前CO2电还原生成甲酸盐研究现状,提出对纳米材料和复合材料进行创新,借助原位表征技术探究活性位点及反应路径,并用于指导高效催化剂的设计与合成,改进电化学反应器组件以提高催化效率等问题可以作为未来的研究重点和发展方向。

     

    Abstract: This paper reviews the latest progress in the field of CO2 electrocatalytic reduction to formate in the past five years. The reaction mechanism of CO2 electroreduction to formate and the types of catalysts used in this process are introduced, including metal catalysts, atomic dispersion catalysts, metal oxide catalysts, carbon materials, and composite material catalysts. The main factors affecting product selectivity, catalytic activity and stability are analyzed in detail from the perspectives of catalyst, electrolyte, reaction atmosphere and electrolytic cell. In view of the current research status of carbon dioxide electroreduction to formate, it is proposed to innovate on nanomaterials and composites, explore the active site and reaction path with the help of in-situ characterization technology, and guide the design and synthesis of efficient catalysts, improve the electrochemical reactor module to improve the catalytic efficiency and other issues can be regarded as the future research focus and development direction.

     

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