一种煤与两种城市污水污泥混合热解的热重分析

Thermogravimetric analysis of co-pyrolysis of coal with different municipal sewage sludge

  • 摘要:  采用热重分析法对一种煤和两种城市污水污泥(S1和S2)及其混合物进行了热解实验研究,揭示了煤和污泥在氮气中的热解特性及污泥对煤热解特性的影响。煤和污泥的热解特性参数不同,主要表现在总失重率、失重速率及挥发分析出温度区间等。煤与污泥S1混合有助于增加样品的热解总失重率,提高失重速率;污泥S1与煤的挥发分析出区间部分重合,污泥灰中含的无机物对煤的热解起到催化效果;煤和S2污泥混合后热解反应过程中无明显相互作用;煤与城市污水污泥混合物的相互作用与样品特性和混合比例有关。

     

    Abstract:  Pyrolysis experiments of coal, two kinds of municipal sewage sludge (S1 and S2) and the mixture were carried out in nitrogen atmosphere by thermogravimetric analysis. The pyrolysis characteristics of the coal and the municipal sewage sludge samples and the effects of sewage sludge on coal pyrolysis were studied. The coal and sewage sludge have different pyrolysis characteristics parameters in aspects of total weight loss, weight loss rate and volatile release temperature range. Appropriate mixing of S1 and coal is beneficial to the increase in the total weight loss and weight loss rate of pyrolysis reaction. There is partial overlap between the volatile release ranges of S1 and the coal. The inorganic matter in sewage sludge ash has catalytic effect on coal pyrolysis. The pyrolysis of the mixture of coal and S2 shows no obvious synergistic effect. The pyrolysis characteristics of the mixture of coal and municipal sewage sludge are related to the characteristics of samples and the mixing ratio.

     

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