Abstract:
The gasification characteristics of Huolinhe lignite char (HLH char), SM bituminous coal char (SM char) and Jincheng anthracite char (JC char) with the mixtures of steam and H
2 at elevated pressures were investigated in a pressurized fixed bed differential (PFBD) reactor. The results show that the inhibition of H
2 on the coal-char gasification with steam is remarkable, and the intensity of the inhibition increases with increasing H
2 partial pressure, total pressure and coal rank, respectively; while it decreases with increasing temperature. Coal-char gasification with steam or steam/H
2 can be described by the same kinetic model, and the final carbon conversion of coal-char gasification with steam/H
2 is lower than that with steam. The inhibition mechanism is related to the H
2 partial pressure. When H
2 partial pressure is low, H atom dissociated from H
2 molecule occupies the active point on the coal-char surface directly; while when the H
2 partial pressure is high, the irreversible reaction of oxygen-exchange reaction is strengthened.