Fe的分散程度对煤焦催化加氢气化的影响

Effect of dispersion degree of iron on catalytic hydrogasification of coal char

  • 摘要: 在加压固定床反应器上研究了Fe催化剂在不同比表面积煤焦中分散性对催化加氢气化性能的影响,利用XRD、BET、H2-TPR、FT-IR、TEM、拉曼光谱对煤焦及催化剂进行了分析表征。结果表明,煤焦活性位点和石墨化程度并非影响催化气化反应的唯一因素,而催化剂的分散性对反应影响更大。煤焦的比表面积越大,Fe催化剂在煤焦表面的分散更均匀,催化剂活性组分平均晶粒粒径越小,并可以促进煤催化加氢气化中间相产物Fe3C的生成,甲烷收率越高。对于比表面积较高的900-char,在氢气压力为2 MPa,温度为750 ℃,Fe负载量为5%(质量分数)时,催化加氢气化甲烷收率可达53%。在900-char上考察了Fe催化剂负载量对催化加氢气化的影响,甲烷收率呈先增加后降低的趋势,Fe负载量存在饱和点。

     

    Abstract: The effect of dispersibility of Fe on coal chars with different specific surface areas on the catalytic hydrogasification performance was studied in a pressurized fixed bed reactor. The chars and catalysts were characterized by XRD, BET, H2-TPR, FT-IR, TEM and Raman spectroscopy. The results show that the active site and graphitization degree of coal char are not the only factors affecting the catalytic gasification reaction, but the dispersion of catalyst has a greater impact on the reaction. The larger the specific surface area of coal char is, the more uniform the Fe catalyst disperses on the surface of coal char and the smaller the average grain size of the active component of catalyst is, which can promote the formation of the catalytically hydrogenated mesophase product Fe3C and methane yield. For 900-char with higher specific surface area, the methane yield can reach 53% when the hydrogen pressure is 2 MPa, the temperature is 750℃ and the Fe loading is 5%. The effect of Fe catalyst loading on the catalytic hydrogasification was investigated with 900-char. It is found that the methane yield increases first and then decreases, and the Fe loading has a saturation point.

     

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