Abstract: With H₂WO₄ and EDA as precursors, WO₃/C intermediate was obtained by mechanical stirring and in-situ solid-phase pyrolysis, then WS₂/C composite material was obtained by high temperature vulcanization. The WS₂/C composite was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and other instrumental analysis methods. At the same time, the electrocatalytic performance of the catalyst was analyzed by the electrocatalytic steady-state polarization curve (LSV), Tafel slope (Tafel), cycle stability (CP), electrochemical impedance (PEIS) and electrochemically active surface area (ECSA) tests of the material. The results show that when the current density of the WS₂/C composite is 10 mA/cm², overpotential is 179 mV, and Tafel slope is 98 mV/dec.