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Refined Ni, Co-induced synthesis of NiCoP nanoparticles uniformly embedded in NCNTs: A robust dual-functional electrocatalyst for water splitting

ZHANG Xupeng WANG Ying LIU Qun ZHANG Yu CHEN Li ZHAN Junling WANG Jiabo

张旭鹏, 王莹, 刘群, 张钰, 陈黎, 展俊岭, 王嘉博. Ni, Co诱导合成嵌有高分散NiCoP纳米粒子的NCNTs:一种高效的双功能电解水催化剂[J]. 燃料化学学报(中英文), 2024, 52(8): 1173-1183. doi: 10.1016/S1872-5813(24)60446-9
引用本文: 张旭鹏, 王莹, 刘群, 张钰, 陈黎, 展俊岭, 王嘉博. Ni, Co诱导合成嵌有高分散NiCoP纳米粒子的NCNTs:一种高效的双功能电解水催化剂[J]. 燃料化学学报(中英文), 2024, 52(8): 1173-1183. doi: 10.1016/S1872-5813(24)60446-9
ZHANG Xupeng, WANG Ying, LIU Qun, ZHANG Yu, CHEN Li, ZHAN Junling, WANG Jiabo. Refined Ni, Co-induced synthesis of NiCoP nanoparticles uniformly embedded in NCNTs: A robust dual-functional electrocatalyst for water splitting[J]. Journal of Fuel Chemistry and Technology, 2024, 52(8): 1173-1183. doi: 10.1016/S1872-5813(24)60446-9
Citation: ZHANG Xupeng, WANG Ying, LIU Qun, ZHANG Yu, CHEN Li, ZHAN Junling, WANG Jiabo. Refined Ni, Co-induced synthesis of NiCoP nanoparticles uniformly embedded in NCNTs: A robust dual-functional electrocatalyst for water splitting[J]. Journal of Fuel Chemistry and Technology, 2024, 52(8): 1173-1183. doi: 10.1016/S1872-5813(24)60446-9

Ni, Co诱导合成嵌有高分散NiCoP纳米粒子的NCNTs:一种高效的双功能电解水催化剂

doi: 10.1016/S1872-5813(24)60446-9
详细信息
  • 中图分类号: O646.5

Refined Ni, Co-induced synthesis of NiCoP nanoparticles uniformly embedded in NCNTs: A robust dual-functional electrocatalyst for water splitting

Funds: The project was supported by Scientific and Technological Research Planning Project of the 13th Five Year Plan of Jilin Provincial Department of Education (JJKH20200237KJ, JJKH20210233KJ), the Fund of Jilin Institute of Chemical Technology (2020 No. 22, 2021 No. 20, 2021 No. 48), Jilin Scientific and Technological Development Program, the Central Guide Local Scientific and Technological Development Fund, Jilin Province Natural Science Fund (YDZJ202201ZYTS405).
More Information
  • 摘要: 通过一步磷化碳化直接合成了Ni、Co诱导的高度分散的NiCoP纳米颗粒嵌入氮掺杂碳纳米管(NiCo/NiCoP-NCNTs)。NiCo/NiCoP-NCNTs作为水分解的双功能电催化剂,在0.5 mol/L H2SO4和1 mol/L KOH溶液中分别仅需206 mV的HER过电位和360 mV的OER过电位。NiCo/NiCoP-NCNTs在10 mA/cm2的电流密度下表现出稳定的1.68 V电池电压,在48 h仅有10%的电流密度下降,表现出卓越的稳定性。催化活性的增强归因于NiCoP纳米颗粒的整合以及NCNTs和NiCo合金之间的协同作用。此外,改善的电催化活性与增加的电化学活性比表面积和降低的电子传递电阻有关。总体而言,NiCo/NiCoP-NCNTs在高效水电解应用中展现出显著的性能。
  • FIG. 3305.  FIG. 3305.

    FIG. 3305.  FIG. 3305.

    Figure  1  Synthesis diagram of NiCo/NiCoP-NCNTs

    Figure  2  (a), (b) SEM images of NiCo/NiCoP-NCNTs catalyst and (c), (d) SEM images of NGL material

    Figure  3  HRTEM images of (a)−(c) NiCoP-NCNTs and (d), (e) NGL, (f) SAED, (g)−(n) EDS and elements mapping results of NiCoP-NCNTs samples

    Figure  4  (a) XRD of NiCo/NiCoP-NCNTs and NGL,(b) nitrogen adsorption-desorption curves

    Figure  5  XPS spectra of NiCo/NiCoP-NCNTs and NGL(a): survey; (b): C 1s; (c): N 1s; (d): P 2p; (e): Ni 2p; (f): Co 2p high resolution spectra.

    Figure  6  (a), (b) LSV and Tafel slopes of HER; (c) CV of NiCo/NiCoP-NCNTs; (d), (e), (f) Cdl, EIS and stability test of NiCo/NiCoP-NCNTs and NGL (all the electrolytes are 0.5 mol/L H2SO4)

    Figure  7  (a), (b) LSV and Tafel slopes of OER. (c) CV of NiCo/NiCoP-NCNTs. (d), (e), (f) Cdl, EIS, stability test of NiCo/NiCoP-NCNTs and NGL (all the electrolytes are 1 mol/L KOH)

    Figure  8  (a), (b) Mass normalized LSV polarization curve; (c), (d) TOF curves of NiCo/NiCoP-NCNTs

    Table  1  Electrochemical performance of bifunctional catalysts HER and OER

    Catalyst ηHER/V ηOER/V Ecell/V Reference
    NiCo/NiCoP-NCNTs 206 360 1.68 this work
    Ni2P-NCNTs 260 410 1.94 this work
    CoP-NCNTs 225 490 1.89 this work
    NiCoP NWAs/NF 197 370 1.64@20 [31]
    NiCo2N/NF 180 290 1.70 [32]
    Ni@NC-800 205 280 1.60 [33]
    Ni-Fe-P-350 182 271 1.68 [34]
    NiFe-NC 197 271 1.67 [35]
    Co/PNC 298 370 1.64 [36]
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  • 收稿日期:  2023-12-29
  • 修回日期:  2024-01-31
  • 录用日期:  2024-03-06
  • 网络出版日期:  2024-04-13
  • 刊出日期:  2024-08-01

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