负载NiO-Fe<sub>2</sub>O<sub>3</sub>的凹凸棒石对生物油模型物催化重整制氢性能的影响

王一双; 陈明强; 刘少敏; 杨忠连; 沈朝萍; 刘珂

负载NiO-Fe₂O₃的凹凸棒石对生物油模型物催化重整制氢性能的影响

1.
安徽理工大学地球与环境学院, 安徽淮南 232001;
2.
安徽理工大学化学工程学院, 安徽淮南 232001

基金项目: 国家自然科学基金(21376007)和国家科技支撑计划项目(2014BAD02B03)资助

详细信息

通讯作者:
陈明强,E-mail:mqchen@aust.edu.cn

中图分类号: TQ517.4
计量
- 文章访问数: 359
- HTML全文浏览量: 14
- PDF下载量: 284
- 被引次数: 0
出版历程
- 收稿日期: 2015-07-07
- 修回日期: 2015-08-28
- 刊出日期: 2015-12-30

Hydrogen production via catalytic steam reforming of bio-oil model compounds over NiO-Fe₂O₃-loaded palygouskite

1.
School of Earth and Environment, Anhui University of Science and Technology, Huainan 232001, China;
2.
School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China

Funds: The project was supported by National Natural Science Foundation of China(21376007) and National Science and Technology Support Project of China(2014BAD02B03).

摘要

摘要: 利用共沉淀法,制备一系列在凹凸棒土上负载不同含量的NiO-Fe₂O₃催化剂。以乙酸、乙醇和苯酚的水溶性溶液为生物油模型物,在自制的三段式固定床反应器中,考察了NiO-Fe₂O₃的负载量、反应温度、水碳比(S/C)对生物油模型物重整制氢的影响。结果表明,所获得的氢气产率最高的工艺条件为,在650℃条件下,以水碳比8~10的生物油模型为实验原料,使用自制的50%NiO-50%Fe₂O₃/PG型催化剂,可使气体产物中H₂的相对含量达到最大66.15%。
- 生物油 /
- 催化重整 /
- 制氢 /
- 凹凸棒土 /
- NiO-Fe₂O₃
Abstract: A series of NiO-Fe₂O₃ catalysts loaded on palygouskite were prepared by co-precipitation method and used in the catalytic steam reforming to produce hydrogen in a self-made three-stage fixed bed reactor. The loading of NiO-Fe₂O₃, reaction temperature and ratio of steam to carbon (S/C) on hydrogen production were investigated, with a water-soluble mixture of acetic acid, ethanol and phenol as the bio-oil model compounds. The results indicated that under the optimum conditions, viz., 650℃, an S/C ratio of 8~10 and 50%NiO-50%Fe₂O₃/PG as the catalyst, the relative content of H₂ reaches 66.15% in the gaseous product.
- bio-oil model compound /
- steam reforming /
- hydrogen production /
- palygouskite /
- NiO-Fe₂O₃

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参考文献(34)

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