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Multi-site Co2P catalyst derived from soybean biomass for dehydrogenation of formic acid

WANG Bixi LIU Zeyu WU Yabei YANG Yanyan YANG Song WANG Xun YE Zi DONG Hongliang ZHU Feng YU Huanhuan LÜ Yingying YU Zhongliang

王碧溪, 刘泽宇, 吴亚北, 杨言言, 杨颂, 王荀, 叶子, 董洪亮, 朱峰, 余焕焕, 吕英英, 余钟亮. 大豆生物质基多位点Co2P催化甲酸脱氢[J]. 燃料化学学报(中英文), 2024, 52(6): 883-892. doi: 10.1016/S1872-5813(23)60410-4
引用本文: 王碧溪, 刘泽宇, 吴亚北, 杨言言, 杨颂, 王荀, 叶子, 董洪亮, 朱峰, 余焕焕, 吕英英, 余钟亮. 大豆生物质基多位点Co2P催化甲酸脱氢[J]. 燃料化学学报(中英文), 2024, 52(6): 883-892. doi: 10.1016/S1872-5813(23)60410-4
WANG Bixi, LIU Zeyu, WU Yabei, YANG Yanyan, YANG Song, WANG Xun, YE Zi, DONG Hongliang, ZHU Feng, YU Huanhuan, LÜ Yingying, YU Zhongliang. Multi-site Co2P catalyst derived from soybean biomass for dehydrogenation of formic acid[J]. Journal of Fuel Chemistry and Technology, 2024, 52(6): 883-892. doi: 10.1016/S1872-5813(23)60410-4
Citation: WANG Bixi, LIU Zeyu, WU Yabei, YANG Yanyan, YANG Song, WANG Xun, YE Zi, DONG Hongliang, ZHU Feng, YU Huanhuan, LÜ Yingying, YU Zhongliang. Multi-site Co2P catalyst derived from soybean biomass for dehydrogenation of formic acid[J]. Journal of Fuel Chemistry and Technology, 2024, 52(6): 883-892. doi: 10.1016/S1872-5813(23)60410-4

大豆生物质基多位点Co2P催化甲酸脱氢

doi: 10.1016/S1872-5813(23)60410-4
详细信息
  • 中图分类号: TQ116.2

Multi-site Co2P catalyst derived from soybean biomass for dehydrogenation of formic acid

Funds: The project was supported by the National Natural Science Foundation of China (22169017, 22366034), Natural Science Foundation of Jiangxi Province (20224BAB203026), the Fundamental Research Program of Shanxi Province (202103021223115), the Science and Technology Project of Jiangxi Education Department (GJJ201709, GJJ2201823, GJJ2201824, GJJ2201830), and the Subsidy Project after R&D Investment of Shangrao City (SKB2021002, 2023AB017, 2023AB014, SKB2021017).
More Information
  • 摘要: 本研究报道了一种通过大豆和钴盐热解制备的甲酸脱氢用Co2P催化剂,制备过程简单且环境友好。催化过程中,催化剂上的含K固体碱可作为路易斯酸性位点促进HCOO中间体的吸附,而自掺杂的N可作为碱性位点促进H+的吸附。大豆生物质中的P可与钴盐结合并热解成Co2P,该位点可裂解HCOO的H−C键。催化剂制备过程中当Co(NO3)2·6H2O/大豆的质量比为1∶15时,所得Co2P催化剂对甲酸脱氢反应的产气率可达237.47 mL/(g·h),并展现出良好的稳定性。本研究结果可为甲酸选择性产氢用非贵金属非均相催化剂的开发提供一定的借鉴基础。
  • FIG. 3165.  FIG. 3165.

    FIG. 3165.  FIG. 3165.

    Figure  1  Synthesis of Co2P catalyst for formic acid dehydrogenation

    Figure  2  XRD patterns of different samples

    Figure  3  (a)−(b) SEM and (c) TEM images of soybean-derived C support; (d) EDS spectrum of (Co2P)1-SB15; (e)−(f) TEM images and (g) HAADF-STEM mappings of (Co2P)1-SB15

    Figure  4  TPD-MS profiles of NH3 (a) and CO2 (b) of (Co2P)1-SB15

    Figure  5  XPS spectra of regions for (Co2P)1-SB15

    Figure  6  Gas production rates of (a) (Co2P)1-SB10 synthesized at different pyrolysis temperatures and (b) (Co2P)x-SBy pyrolyzed at 750 °C, (c) volume of gas produced during five cycles and (d) accumulated gas volume in a 63 h-continuous test over (Co2P)1-SB15

    (Reaction conditions: 20 mL of 10.39 mol/L FA, 98 °C)

    Figure  7  (a) XRD patterns of (Co2P)1-SB15 after H2SO4 treatment: (b) Gas production rate comparison of (Co2P)1-SB15 catalyst before and after H2SO4 or KSCN treatment

    (Reaction conditions: 20 mL of 10.39 mol/L FA, 98 °C)

    Figure  8  Possible mechanism of FAD on (Co2P)1-SB15

    Table  1  Co and P contents of catalyst and corresponding FA solution in 10.39 mol/L FA, 98 °C

    Sample Co P Unit
    (Co2P)1-SB15 1.04 0.77 %
    (Co2P)1-SB15-1 h 0.86 0.28 %
    (Co2P)1-SB15-63 h 0.81 0.27 %
    FA solution-63 h 95.3 139.3 mg/L
    下载: 导出CSV

    Table  2  K contents of (Co2P)1-SB15 collected after 1 h and 63 h reaction in 10.39 M FA, 98 °C

    Sample K Unit
    (Co2P)1-SB15-1 h 0.59 wt.%
    (Co2P)1-SB15-63 h 0.13 wt.%
    下载: 导出CSV
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  • 收稿日期:  2023-12-15
  • 修回日期:  2024-01-21
  • 录用日期:  2024-01-24
  • 网络出版日期:  2024-02-26
  • 刊出日期:  2024-06-01

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